Page 8 - 《含能材料》2018年优秀论文
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+$,-$% '()?HI’‰ŠL$,-\ˆŽ                                                                         7

         *à+$bcêZº$>o, ˜+$bcŸ~)(
         tuvf&¿º1ÀvïÐ, ¿ºQ™8šA†_Á
         \{3bc1b。MN¿º1Àv*MNbcŸ~
         )1Qìmn。T2, 7¶·¸Ê, Òhbcê1º
         $eŠ, r›œ“ ž©É”, ^ñCrA‡L'(
         )1%aZ©w‡i$%。„…, A+$bc§Ÿt
         πº, DEj]bcŸ~)1 “ P ”, ^*l¿‰Š
         L$bc10³。
           Amndef, t%1¶·gÚbc“”Cr§                                 e.NTO         f.DAAF
         æ EM 1㡊v      [13 - 15,43 - 45] 。˜‰ŠL$ EM ê1t     > 10 ®]yê)bc$j1‰ŠL$ EM •R1¹º( r¯
         πºbc1“” m î b : 4ì, 2 z 9 l。V ê,                   ÝÍÎl, f) o π  π“”( .)
                                                             Fig.10  IntralayeredHBsrepresentedbypurpledash(top)
         ¡ ¡ π  𓔪îxò£ ã¡¤¥1$.À, ^
                                                             andπ  π stacking(bottom)oftypicalLSHEMscomposedof
         h¢ z V . ² 1 ^ ? £ ¤ o ¥ ˜ 1 • O Ÿ 。 2 z10
                                                             neutralmolecules
         oz11 ê1bc?1¹º‘*¦§•OŸ1|0¸









                                                                                 a.TKX50
         a.facetoface  b.wavelike  c.crossing  d.mixing
         > 9 “ìmn“”êbc? / bcR~$(p) ¨©ªÌ(d)
         ?Е( αo βb{gl«¬­o×Òm,¨©)
         Fig.9  Inter/intramolecularpotentialenergy(p)slidingdis
         tance(d)dependencesinfourkindsofcrystalstacking( αandβ
         denotetheslidingalongright/leftandfront/back,respectively)

                                                              b.hydroxylammonium 4aminofarazan3yltetrazol1olate













              a.TATB         b.FOX7                         c.dihydroxylammonium3,3′dinitro5,5′bis1,2,4triazole1,1diolate
                                                             > 11 ‰ŠL$Ìc°ê1 π  π“” (1)o± (2) # (3) Ì
                                                             c²:1bc?¹º
                                                             Fig.11  Theπ  π stacking(1)andintermolecularhydrogen
                                                             bondsaroundanions(2)andcations(3)inLSHEionsalts


                                                             Ê。Ut% EM 1bc?¸Ê¶·gÚ, bc?1¸
                                                             Ê& EM 1$%o'()ZÆÀ1ÐÔ)。2z 12
                                                             l:Àbc?¹º& π  π“””Ù*‰ŠL$ EM
              c.LLM105       d.DAAzF                        1‡.ûü。p0ýÚ1*, bc?ïí¸Ê1MÀ



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