Page 8 - 《含能材料》2018年优秀论文
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+$,-$% '()?HIL$,-\ 7
*à+$bcêZº$>o, +$bc~)(
tuvf&¿º1ÀvïÐ, ¿ºQ8A_Á
\{3bc1b。MN¿º1Àv*MNbc~
)1Qìmn。T2, 7¶·¸Ê, Òhbcê1º
$e, r“ ©É”, ^ñCrAL'(
)1%aZ©wi$%。
, A+$bc§t
πº, DEj]bc~)1 “ P ”, ^*l¿
L$bc10³。
Amndef, t%1¶·gÚbcCr§ e.NTO f.DAAF
æ EM 1ã¡v [13 - 15,43 - 45] 。L$ EM ê1t > 10 ®]yê)bc$j1L$ EM R1¹º( r¯
πºbc1 m î b : 4ì, 2 z 9 l。V ê, ÝÍÎl, f) o π π( .)
Fig.10 IntralayeredHBsrepresentedbypurpledash(top)
¡ ¡ π πªîxò£ 㡤¥1$.À, ^
andπ π stacking(bottom)oftypicalLSHEMscomposedof
h¢ z V . ² 1 ^ ? £ ¤ o ¥ 1 O 。 2 z10
neutralmolecules
oz11 ê1bc?1¹º*¦§O1|0¸
a.TKX50
a.facetoface b.wavelike c.crossing d.mixing
> 9 ìmnêbc? / bcR~$(p) ¨©ªÌ(d)
?Ð( αo βb{gl«¬o×Òm,¨©)
Fig.9 Inter/intramolecularpotentialenergy(p)slidingdis
tance(d)dependencesinfourkindsofcrystalstacking( αandβ
denotetheslidingalongright/leftandfront/back,respectively)
b.hydroxylammonium 4aminofarazan3yltetrazol1olate
a.TATB b.FOX7 c.dihydroxylammonium3,3′dinitro5,5′bis1,2,4triazole1,1diolate
> 11 L$Ìc°ê1 π π (1)o± (2) # (3) Ì
c²:1bc?¹º
Fig.11 Theπ π stacking(1)andintermolecularhydrogen
bondsaroundanions(2)andcations(3)inLSHEionsalts
Ê。Ut% EM 1bc?¸Ê¶·gÚ, bc?1¸
Ê& EM 1$%o'()ZÆÀ1ÐÔ)。2z 12
l:Àbc?¹º& π πÙ*L$ EM
c.LLM105 d.DAAzF 1.ûü。p0ýÚ1*, bc?ïí¸Ê1MÀ
CHINESEJOURNALOFENERGETICMATERIALS !"#$ 2018% & 26' & 1( (2 - 10)