CHINESE JOURNAL OF ENERGETIC MATERIALS
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Pore Collapse and Hot Spot Formation Mechanisms in HMX Crystals under Moderate Shock Pressure
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National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, CAEP

Fund Project:

Grant support: Science Challenge Project(No. TZ2025001);National Natural Science Foundation of China (No. 11902306)

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    Abstract:

    Hot spots are critical initiators of both shock-induced detonation and non-shock ignition in explosives, with pore collapse as a primary formation mechanism. Since energetic materials are routinely subjected to complex mechanical loading across a broad intensity range during service, a mechanistic understanding of pore evolution and hot-spot generation under moderate shock pressures (1-10 GPa) is essential for reliable safety assessment. In this study, HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine) crystals containing a 300 μm prefabricated pore were investigated. High-speed imaging combining X-pinch and visible-light diagnostics captured the dynamic pore collapse process, while thermomechanically coupled numerical simulations accounted for the conversion of plastic work into thermal energy. The results reveal distinct pore collapse modes and associated hot-spot formation mechanisms. At 2.5 GPa, the isotropic pore collapse mechanism was observed, with hot spot intensity correlating positively with the extent of pore collapse. The temperature rise occurs in two stages: an initial gradual increase due to upstream viscoplastic deformation, followed by a sharp temperature rise after pore closure, resulting from the thermal conversion of kinetic energy during the impact of high-velocity upstream material on the downstream pore wall. When the shock pressure is increased to 3.5 GPa, pore collapse initiates earlier, the crescent-shaped deformation becomes more pronounced, and the mechanical response exhibits hydrodynamic behavior, indicating a transition toward jetting-type collapse.

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张可,谢斐骏,杨晓媛,等.中等冲击强度载荷下HMX晶体预制孔洞塌缩及热点生成机制研究[J].含能材料,2026,34(2):111-121.
ZHANG Ke, XIE Fei-jun, YANG Xiao-yuan, et al. Pore Collapse and Hot Spot Formation Mechanisms in HMX Crystals under Moderate Shock Pressure[J]. Chinese Journal of Energetic Materials,2026,34(2):111-121.

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History
  • Received:December 14,2025
  • Revised:February 26,2026
  • Adopted:February 07,2026
  • Online: February 12,2026
  • Published: