CHINESE JOURNAL OF ENERGETIC MATERIALS
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Effect of Morphology Evolution on Mechanical Properties and Sensitivities for FOX-7 Particles Under Thermal Stimulus
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1.Institute of Chemical Materials, CAEP, Mianyang 621999, China;2.China Academy of Engineering Physics, Mianyang 621900, China

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    Abstract:

    In order to study the morphology evolution of 1, 1-diamino-2, 2-dinitroethylene (FOX-7) particles under thermal stimulus and its influence on mechanical properties and mechanical sensitivities, four kinds of FOX-7 particles with typical size and morphology differences were selected. By controlling heating time and temperature, the morphology, mechanical properties and mechanical sensitivities evolutions of FOX-7 particles after heating were studied by scanning electron microscope, compressive stiffness experiment and mechanical sensitivities tests. The results show that the surface cracks of FOX-7 particles appear after heating and returning to room temperature. With the increase of heating temperature or heating time, the surface cracks of large-size particles (>100 μm) grow and break through , thus the particles crack in layers and exfoliate. While, the surface cracks of small-sized particles (<100 μm) do not grow with the increase of heating temperature or heating time. Kawakita equation was used to fit the compaction curves of FOX-7 particles before and after heating. It is found that the modulus of FOX-7 particles increase after heating, and the increase is even greater for small particle size. Under the condition of larger particle size, FOX-7 has relatively low mechanical sensitivities, and still maintains low mechanical sensitivities after being heated and returning to room temperature. When the particle size is small, the mechanical sensitivities of FOX-7 are relatively high, and after heating and returning to room temperature, the mechanical sensitivities increase significantly, which may be related to the greater increase of modulus.

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谢虓,艾进,黄靖伦,等.热刺激作用下FOX-7颗粒形貌演化对其力学特性及感度的影响[J].含能材料,2023,31(10):986-993.
XIE Xiao, AI Jin, HUANG Jing-lun, et al. Effect of Morphology Evolution on Mechanical Properties and Sensitivities for FOX-7 Particles Under Thermal Stimulus[J]. Chinese Journal of Energetic Materials,2023,31(10):986-993.

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History
  • Received:March 11,2023
  • Revised:June 09,2023
  • Adopted:June 21,2023
  • Online: July 04,2023
  • Published: October 25,2023