CHINESE JOURNAL OF ENERGETIC MATERIALS
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Failure Causes and Restraining Method of Fiber Contact Laser Ignited Initiators in Temperature Alternation
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1.School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.;2.Sichuan Aerospace Chuannan Initiating Explosive Technology Limited, Luzhou 646000, China

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    Abstract:

    In order to explore the influence of temperature impact and cycling on ignition time of laser pyrotechnics,the laser initiators with carbon doped tetraammine bis(5-nitrotetrazolato) cobalt(Ⅲ) perchlorate (BNCP) as primary explosive and fiber-window structure were employed to study performance of BNCP, structure change of laser initiators and structural constraint between fiber and explosive under different temperature alternating experiments (47 h and 94 h). The experiment results show that the ignition time can reach less than 0.2 ms indicating a great ignition performance before temperature alternating experiment. However, the ignition time delayed more than 0.5 ms after 47 h temperature alternating experiment and some initiators delayed more than 1 ms even misfired after 94 h temperature alternating experiment. The crystal grains of BNCP broke up and the bulk density decreased from 0.43 g·cm-3 to 0.32 g·cm-3 after alternating temperature experiment. However, the change of bulk density has no influence on thermal decomposition and ignition performance. The difference of expansion coefficient between ceramic fiber optic components and igniter shell leads to a gap between fiber and doped BNCP during alternating temperature experiment. The gap has a great influence on both laser spot intensity and hot spot diffusion. With structural constraints of fiber and explosive increasing, the ignition gap can decrease effectively during alternating temperature environment and the environment adaptability of laser initiators can be improved.

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先明春,佟乐乐,矫金福,等.温度交变中光纤接触式激光火工品的失效原因及抑制研究[J].含能材料,2023,31(3):243-250.
XIAN Ming-chun, TONG Le-le, JIAO Jin-fu, et al. Failure Causes and Restraining Method of Fiber Contact Laser Ignited Initiators in Temperature Alternation[J]. Chinese Journal of Energetic Materials,2023,31(3):243-250.

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History
  • Received:August 31,2022
  • Revised:March 20,2023
  • Adopted:March 13,2023
  • Online: March 14,2023
  • Published: March 25,2023