CHINESE JOURNAL OF ENERGETIC MATERIALS
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Combustion Stability of Flake Variable Burning Rate Propellant after High and Low Temperature Cycling
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1.School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China;2.Key Laboratory of Special Energy Materials, Ministry of Education, Nanjing University of Science and Technology, Nanjing 210094, China;3.Luzhou North Chemical Industry Co., Ltd, Luzhou 646605, China

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    Abstract:

    In order to investigate the combustion stability of flake variable burning rate propellant under high and low temperature cycle preservation, based on the morphology of samples and the change of combustion performance, a 20 time thermal cycling treatment was carried out, in which samples were separately stored at 70 ℃ and -50 ℃ for 10 h as one cycle. The surface and section morphology of propellant was observed via optical microscope, and the combustion performance at 50 ℃, 20 ℃, -40 ℃ was tested by closed bomb. Microscopic observation shows that after thermal cycling treatment, the bubbles on the surface increase and the section of propellant becomes lumpy and uneven due to plastic deformation, while the interface between the inner and outer layers remains tight without visible cracks. The combustion performance basically unchanged after thermal cycling treatment, and the dynamic activity curves nearly overlap, for which the maximum ΔLa is 2.57% at low temperature. After thermal cycling treatment, the temperature coefficient under high-pressure from normal to low temperature is significantly lower than that of the original under the same conditions, and the difference in pressure index of the flake variable burning rate propellant at high temperature and low temperature is smaller than that of the original under the same conditions. Attributed to bound interface and combustion consistency, flake variable burning rate propellant has good storage stability under different temperatures.

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赵先正,刘详,丁亚军,等.高低温循环保存下片状变燃速发射药的燃烧稳定性[J].含能材料,2023,31(9):903-909.
ZHAO Xian-zheng, LIU Xiang, DING Ya-jun, et al. Combustion Stability of Flake Variable Burning Rate Propellant after High and Low Temperature Cycling[J]. Chinese Journal of Energetic Materials,2023,31(9):903-909.

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History
  • Received:August 15,2022
  • Revised:July 13,2023
  • Adopted:July 05,2023
  • Online: July 12,2023
  • Published: September 25,2023