CHINESE JOURNAL OF ENERGETIC MATERIALS
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Preparation and Infrared Interference Performance of Nickel-plated Graphene
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1.Laboratory of Pyrotechnical Technology, Institute of NBC Defence, Beijing 102205, China;2.32238 Army, Nanjing 210000, China

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    Abstract:

    In order to investigate the infrared extinction performance of nickel-plated graphene and explore the best formulation, nickel-plated graphene was prepared by the redox and chemical plating methods. The influence of various factors on the extinction performance of nickel-plated graphene was analyzed by designed orthogonal experiments with the infrared decay rate as the evaluation index, and the optimal formulation was determined. The infrared transmittance of nickel-plated graphene was measured in a smoke-screen chamber test. The average mass extinction coefficient of nickel-plated graphene was calculated by linear fitting according to the “Lambert-Beer” law. The results showed that the optimal process parameters for the preparation of nickel-plated graphene were: c(NiSO4·6H2O)=20 g·L-1c(NaH2PO2·H2O)=24 g·L-1c(C6H5Na3O7·2H2O)=10 g·L-1 c(NH4Cl)=30 g·L-1, pH=8-9, and plating temperature of 65 ℃. The nickel-plated graphene prepared under the optimal conditions exhibited good infrared extinction in both mid- and far-infrared wavelengths. The average mass extinction coefficients of the nickel-plated graphene in the infrared bands of 3-5 μm and 8-14 μm were 2.38 m2·g-1 and 2.19 m2·g-1, respectively. Compared with the modified graphene, the average mass extinction coefficients of nickel-plated graphene in the mid-infrared bands were improved by 30% and 35%, respectively, which have broader application prospects.

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李慧莹,王玄玉,孙淑宝,等.镀镍石墨烯制备及红外干扰性能[J].含能材料,2022,30(12):1213-1218.
LI Hui-ying, WANG Xuan-yu, SUN Shu-bao, et al. Preparation and Infrared Interference Performance of Nickel-plated Graphene[J]. Chinese Journal of Energetic Materials,2022,30(12):1213-1218.

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History
  • Received:June 20,2022
  • Revised:September 26,2022
  • Adopted:September 21,2022
  • Online: September 21,2022
  • Published: December 25,2022