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Effect of Binder on Formability and Combustion Performance of B/KNO3 Samples by Direct Ink Writing
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1.School of Environment and Safety Engineering, North University of China, Taiyuan 030051, China;2.Shanxi Engineering Technology Research Centre for Ultrafine Powder, Taiyuan 030051, China;3.Chuannan Aerospace Energy Technology Co., Ltd, Luzhou 646000, China

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    Abstract:

    In order to design the B/KNO3 (BPN) ignition powder formula with good combustion performance and compatibility with the direct ink writing technology, seven BPN-based ignition powder ink were designed and prepared by direct ink writing technology with different binders including polyvinylidene fluoride (PVDF), poly (vinylidene fluoride-trifluorochloroethylene) F2311, poly (vinylidene fluoride-hexafluoropropylene) F2602, poly (vinylidene fluoride-hexafluoropropylene-tetrafluoroethylene) F2461, ethylcellulose (EC), nitrocellulose (NC) and PVDF/NC. The effects of different binder on the formability, ignition/combustion and thermal decomposition performance were investigated. The results show that the change of binder composition could result in the differentiation of the consistency index of BPN ink. The order of consistency index of different ink is EC/B/KNO3>PVDF/B/KNO3>PVDF/NC/B/KNO3>NC/B/KNO3>F2311/B/KNO3>F2602/B/KNO3>F2461/B/KNO3. The formability of the ink depend on its consistency index. The rectangularity variation tendency of the samples prepared by direct ink writing technology is consistent with the consistency index. The BPN-based ignition powder containing fluorine rubber presented a higher burning rate and a shorter ignition delay. Meanwhile, the burning rate is faster when the H content is higher in the fluorine rubber. The order of linear burning rate of the BPN-based ignition powder containing different rubber is: PVDF/B/KNO3>F2602/B/KNO3>PVDF/NC/B/KNO3>NC/B/KNO3>F2461/B/KNO3>F2311/B/KNO3>EC/B/KNO3. However, cellulose binder did not present any significant contribution to reduce the ignition delay. Adding fluorine rubber can reduce the initial reaction temperature of BPN-based ignition powder by about 145 ℃. NC can reduce the initial reaction temperature of the main reaction of the powder by 45 ℃. The addition of EC can only reduce the initial reaction temperature of the main reaction by about 5 ℃.

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李晨阳,文坤,安崇伟,等.黏结剂对B/KNO3微笔直写样品成型效果及燃烧性能的影响[J].含能材料,2022,30(4):332-340.
LI Chen-yang, WENG Kun, AN Chong-wei, et al. Effect of Binder on Formability and Combustion Performance of B/KNO3 Samples by Direct Ink Writing[J]. Chinese Journal of Energetic Materials,2022,30(4):332-340.

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History
  • Received:November 08,2021
  • Revised:February 22,2022
  • Adopted:February 17,2022
  • Online: February 19,2022
  • Published: April 25,2022