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Safety Performance of FOX-7 Based Casting PBX
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Institute of Chemical Materials, CAEP, Mianyang 621999, China

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    Abstract:

    In order to improve the safety performance of cyclotetramethylenetetranitramine (HMX) based cast polymer bonded explosive (PBX), a certain amount of 1,1-diamino-2,2-dinitroethylene (FOX-7) was substituted for HMX in the formulation. The influence of FOX-7 on the thermal stability, mechanical sensitivity, shock wave sensitivity and electrostatic spark sensitivity of the formulation was studied. The friction sensitivity of the formulation GOXL-A was lower than that of the HMX based cast PBX formulation GO-1 after the introduction of FOX-7. The response time in the fast cook-off and slow cook-off tests was delayed by 58.8% and 18.5%, respectively. The formulation had passed the EIS slow cook-off test with a heating rate of 3.3 ℃·h-1. The shock wave sensitivity was significantly reduced. The separator thickness (L50) was reduced by 15.7% compared with GO-1, and the 50% critical detonation pressure (p50) was increased by 9.5%. Its static spark sensitivity is significantly reduced. The 50% ignition voltage (V50) and 50% ignition energy (E50) increased by 65.3% and 187.5%, respectively.

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谢虓,王述存,黄川,等. FOX-7基浇注型PBX安全性能[J].含能材料,2019,27(11):942-948.
XIE Xiao, WANG Shu-cun, HUANG Chuan, et al. Safety Performance of FOX-7 Based Casting PBX[J]. Chinese Journal of Energetic Materials,2019,27(11):942-948.

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History
  • Received:June 13,2019
  • Revised:July 07,2019
  • Adopted:August 15,2019
  • Online: November 27,2019
  • Published: November 25,2019