CHINESE JOURNAL OF ENERGETIC MATERIALS
+Advanced Search

Preparation and Performance of Self-healing Binder Based on GAP
Author:
Affiliation:

School of Chemistry Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Fund Project:

  • Article
  • |
  • Figures
  • |
  • Metrics
  • |
  • Reference
  • |
  • Related
  • |
  • Cited by
  • |
  • Materials
    Abstract:

    To prolong the storage life of binder, the poly(glycidyl azide) ether(GAP)-based binders with self-healing performance were firstly synthesized by introducing disulfide functional group into an azide binder through an one-step method. Fourier transform infrared spectroscopy(FTIR), X-ray diffractometry(XRD) and optical microscopy were used to characterize its structure and surface topography characterization. On this basis, the self-healing efficiency under different self-healing temperature and different self-healing time was examined through the change of tensile strength before and after self-healing. Results show that the synthesized GAP-based self-healing binder has a polyurethane structure, the surface cracks of self-healing binder are completely healed after 24 h at 60 ℃. Increasing the temperature and prolonging the self-healing time are helpful to improve the self-healing efficiency. At the same time, the self-healing efficiency is firstly improved and then decreased with increasing mass fraction of the cross-linking agent, in which, the self-healing efficiency for the formula with a cross-linker mass fraction of 8% can reach 98%. Compared with control sample with the self-healing efficiency as 61.7%, which proves that the introduction of disulfide functional groups can improve the self-healing efficiency of the system.

    Reference
    Related
    Cited by
Article Metrics
  • PDF:
  • HTML:
  • Abstract:
  • Cited by:
Get Citation

菅晓霞,宋育芳,赵盟辉,等. GAP基自修复粘结剂的制备及性能[J].含能材料,2019,27(2):131-136.
JIAN Xiao-xia, SONG Yu-fang, ZHAO Meng-hui, et al. Preparation and Performance of Self-healing Binder Based on GAP[J]. Chinese Journal of Energetic Materials,2019,27(2):131-136.

Cope
History
  • Received:June 26,2018
  • Revised:November 30,2018
  • Adopted:September 07,2018
  • Online: October 31,2018
  • Published: February 25,2019