CHINESE JOURNAL OF ENERGETIC MATERIALS
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Rapid Test of Modified Double-base Propellant Component Uniformity by NIR Spectroscopy
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(1. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China; 2. Shanxi North Xing′an Chemical Industry Co. LTD, Taiyuan 030008, China)

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    Abstract:

    To establish a rapid quantitative test method of blending uniformity of modified double-base propellant components, a near infrared (NIR) spectrometer was adopted to test the double-base absorbed sample and to quantitatively analyze the contents of each component and their dispersion uniformity. Firstly, based on sample testing, the quantitative calibration models of the components: nitrocellulose(NC), nitroglycerine(NG), cyclotrimethylenetrinitramine(RDX) and water were established and the correlation coefficients of each component model are more than 0.98, and the mean values of components′ absolute errors obtained by internal validation are less than 2%. Then NIR spectra of samples in the blending process were continually collected. The component contents of sample were predicted by the established models. The absolute errors of the predicted results and the actual values are less than 2%. The blending uniformity of sample was analyzed by coefficient of variation (CV) method for the contents of each component and and moving block standard deviation (MBSD) method for the original spectra of samples. The CV values of each component are less than 1.5%, while MBSD value of the sample is less than 0.001. Two kinds of evaluation indexes have reached steady state after 2.5 min, indicating that sample components had uniform distribution. Results show that it is feasible to use near infrared (NIR) spectroscopy to test the blending uniformity of modified double-base propellant components.

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程士超,蔺向阳,李燕,等.近红外光谱法快速测试改性双基推进剂组分的均匀性[J].含能材料,2016,24(4):343-347.
CHENG Shi-chao, LIN Xiang-yang, LI Yan, et al. Rapid Test of Modified Double-base Propellant Component Uniformity by NIR Spectroscopy[J]. Chinese Journal of Energetic Materials,2016,24(4):343-347.

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History
  • Received:May 18,2015
  • Revised:June 18,2015
  • Adopted:July 07,2015
  • Online: March 29,2016
  • Published: April 15,2016