CHINESE JOURNAL OF ENERGETIC MATERIALS
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Preparation and Characterization of a Novel HMX/AP/EP Nanocomposite
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(State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials Key Laboratory Southwest University of Science and Technology, Mianyang 621010, China)

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    Abstract:

    The cyclotetramethylene tetranitramine (HMX)/ammonium perchlorate (AP)/energetic polymer (EP) nanocomposite was prepared by a co-precipitation method using a novel EP as matrix. Its structure and properties were characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), specific surface area (Brunauer-Emmett-Teller (BET)) measurement, Infrared (IR) spectrometry, and differential scanning calorimetry (DSC). Results show that the HMX/AP/EP nanocomposite possesses the three-dimensional nano-network structure. The HMX and AP particles are uniformly deposited on EP, whose size is in the range of 50-200 nm. HMX, AP and EP are closely bonded each other with good compatibility. The thermal decomposition temperature of the HMX/AP/EP nanocomposite is far lower than that of HMX. When the oxygen balance of HMX/AP/EP nanocomposite is zero, its decomposition heat is up to 2570 J·g-1.Compared with the characteristic drop height of impact sensitivity (H50) of 27 cm of HMX, the value of H50 of the HMX/AP/EP nanocomposite is 50.49 cm, revealing that the latter has lower mechanical sensitivity.

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廖宁,李兆乾,李文鹏,等.新型HMX/AP/EP纳米复合物的制备及表征(英)[J].含能材料,2015,23(7):709-711.
LIAO Ning, LI Zhao-qian, LI Wen-peng, et al. Preparation and Characterization of a Novel HMX/AP/EP Nanocomposite[J]. Chinese Journal of Energetic Materials,2015,23(7):709-711.

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History
  • Received:October 12,2014
  • Revised:December 26,2014
  • Adopted:January 05,2015
  • Online: June 10,2015
  • Published: June 17,2015