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Mass Transfer Reaction Process of NO Gas Absorbed by FeⅡ(EDTA)2- Solution
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(Research Center of Shanxi Province for High Gravity Chemical Engineering and Technology, North University of China ,Taiyuan 030051,China)

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    Abstract:

    NO is difficult to be rapidly oxidized and absorbed in the wet oxidation method used in the treatment of the NOx exhaust gases produced in the production process of propellants and explosives, which cause the low absorption rate.To solve this problem, ferrous complex Fe(EDTA)2-(Ethylene Diamine Tetraacetic Acid, EDTA)was used as the absorbent of NO in a bubbling reactor.The effects of absorbing solution concentration and NO gas concentration on the absorption rate were investigated.The mass transfer-reaction process of NO absorption was analyzed.The theoretical model describing the NO absorption process was derived.Results show that:under experimental conditions, the absorption rate increases linearly with the increase of NO concentration, and the NO absorbed by Fe(EDTA)2- is a pseudo first-order reaction process.The error between calculated values obtained by absorption process model and experimental ones is within 5%, both have good consistency, which can be used to describe the mass transfer-reaction process of NO absorbed by Fe(EDTA)2- solution.

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王菲,刘有智,袁志国,等. FeⅡ(EDTA)2-溶液吸收NO气体的传质-反应过程[J].含能材料,2015,23(3):285-290.
WANG Fei, LIU You-zhi, YUAN Zhi-guo, et al. Mass Transfer Reaction Process of NO Gas Absorbed by FeⅡ(EDTA)2- Solution[J]. Chinese Journal of Energetic Materials,2015,23(3):285-290.

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History
  • Received:June 30,2014
  • Revised:July 05,2014
  • Adopted:July 21,2014
  • Online: March 09,2015
  • Published: March 10,2015