A novel energetic compound, N, N′-dinitro-N, N′-bis methylenediamine, was synthesized using 3-amino-4-(t-Bu-NNO-azoxy)furazan as starting material. And its structure was characterized by nuclear magnetic resonance (¹H NMR and ¹³C NMR), infrared (IR) spectroscopy, elemental analysis and mass spectrometry, and its backbone was also confirmed by the X-ray structure study of the key intermediate. The detonation performance was calculated by VLW equation of state. Results show density is 1.94 g·cm^-3, detonation velocity 9502.52 m·s^-1, detonation pressure 41.79 GPa and enthalpy of formation 1007.67 kJ·mol^-1, indicating it is a competitive energetic materials.