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Characterization Viscoelastic Properties of Multi-walled Carbon Nanotubes/F2314 Composites Using DMA Method
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(Institute of Chemical Materials, CAEP, Mianyang 621999, China)

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    Abstract:

    Multi-walled carbon nanotubes (MWCNTs)/fluoropolymer (F2314) composites were prepared via a melt blending process The influences of MWCNTs content on the viscoelastic properties (dynamic mechanical behavior and three-point bending creep properties of MWCNTs/F2314) were explored using dynamic mechanical analysis (DMA) method. The results show that with increasing the MWCNTs content, the storage modulus (E′) of MWCNTs/F2314 composites increases, the glass transition temperature (Tg) and peak value of loss factor (tanδmax) decrease. The creep strain and constant creep strain rate of MWCNTs/F2314 composites distinctly decrease due to the presence of MWCNTs. At 80 ℃/0.1 MPa, when the MWCNTs content(mass fraction) increases from 2% to 20%, the creep strain and constant creep strain rate of MWCNTs/F2314 composites decrease by 87.6% and 84.7%, respectively. Burger four-element mechanical model can be used to simulate the creep behaviors of MWCNTs/F2314 composites and obtain the constitutive equations of creep curves.

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林聪妹,刘佳辉,刘世俊,等. DMA方法研究多壁碳纳米管/F2314复合材料的粘弹性能[J].含能材料,2015,23(2):140-145.
LIN Cong-mei, LIU Jia-hui, LIU Shi-jun, et al. Characterization Viscoelastic Properties of Multi-walled Carbon Nanotubes/F2314 Composites Using DMA Method[J]. Chinese Journal of Energetic Materials,2015,23(2):140-145.

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History
  • Received:November 17,2013
  • Revised:January 06,2014
  • Adopted:February 25,2014
  • Online: February 09,2015
  • Published: February 12,2015