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Synthesis of 6-Dinitroethylene-4,5,8-trinitro-5,6,7,8- tetrahydro-4H-imidazo[4,5-e] furazano[3,4-b]piperazine
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(Xi′an Modern Chemistry Research Institute, Xi′an 710065)

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    Abstract:

    A novel energetic compound, 6-dinitroethylene-4, 5, 8-trinitro -5, 6, 7, 8-tetrahydro -4H-imidazo [4, 5-e] furazano [3, 4-b] piperazine (PNEIFP), was designed and synthesized from glyoxal and FOX-7 by two cyclizations and nitration. In addition, some properties of PNEIFP were calculated by Gaussian 09 program and VLW formula. The results show that its density is 2.02 g·cm-3, and the detonation velocity is 9681.0 m·s-1, and the enthalpy of formation is 724.1 kJ·mol-1. PNEIFP easily decomposes at room temperature.

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霍欢,王伯周,廉鹏,等.6-偕二硝基乙烯基-4,5,8-三硝基-5,6,7,8-四氢化-4H-咪唑烷并[4,5-e]呋咱并[3,4-b]哌嗪的合成(英)[J].含能材料,2014,22(2):274-275.
HUO Huan, WANG Bo-zhou, LIAN peng, et al. Synthesis of 6-Dinitroethylene-4,5,8-trinitro-5,6,7,8- tetrahydro-4H-imidazo[4,5-e] furazano[3,4-b]piperazine[J]. Chinese Journal of Energetic Materials,2014,22(2):274-275.

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History
  • Received:August 28,2013
  • Revised:October 31,2013
  • Adopted:December 02,2013
  • Online: April 28,2014
  • Published: April 24,2014