CHINESE JOURNAL OF ENERGETIC MATERIALS
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Effect of Refining on the Properties of 5,7-Diamino-4,6-dinitrobenzenfuroxan
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(School of Chemical Engineering, NUST, Nanjing 210094, China)

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    Abstract:

    In order to study the properties of 5, 7-diamino -4, 6-dinitrobenzenfuroxan(CL-14), CL-14 was refined via recrystallization of potassium salt of CL-14, acidification at high temperature and acid elimination under heating. The sensitivity and thermal stability of unrefined CL-14 and refined CL-14 were tested by the standardization method GJB772A-1997. The peak temperature of exothermic decomposition reaction of unrefined CL-14 and refined CL-14 was determined by DSC. Results show that the pH of refined CL-14 is 6.5. The impact sensitivity and friction sensitivity are 24% and 16% respectively. The amount of gas evolved of refined CL-14 obtained by Vacuum Stability Test with 200 ℃/48 h is 0.81 mL·g-1.The peak temperature of exothermic decomposition reaction of refined CL-14 is 313.7 ℃, 13.7 ℃ higher than that of the unrefined CL-14, showing that the refined CL-14 has lower acidity and better thermal stability.

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董岩,刘祖亮.精制对5,7-二氨基-4,6-二硝基苯并氧化呋咱性能的影响[J].含能材料,2013,21(6):706-710.
DONG Yan, LIU Zu-liang. Effect of Refining on the Properties of 5,7-Diamino-4,6-dinitrobenzenfuroxan[J]. Chinese Journal of Energetic Materials,2013,21(6):706-710.

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History
  • Received:December 24,2012
  • Revised:February 07,2013
  • Adopted:April 09,2013
  • Online: December 06,2013
  • Published: