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Mechanical Properties for DNTF/RDX-CMDB Propellants at Low Temperature
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(Xi′an Modern Chemistry Research Institute, Xi′an 710065, China)

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    Abstract:

    Influence of different ratios of 1,3,5-trinitrohexahydrotriazine(RDX) to 3,4-bisnitrofurazan-furoxan(DNTF) on the mechanical properties of DNTF/RDX composite modified double-base(CMDB) propellant (DNTF/RDX-CMDB, DFR propellant) was studied by uniaxial tensile test, charpy impact test and dynamic mechanical analyzer.The tensile strength (σm), elongation at the maximum stress(εm) and impact strength(aK) of DFR propellant at -40 ℃ were obtained. The dynamical characteristics (viscoelastic coefficients C1g) of β -relaxation was acquired by WLF equation according to the "Time-Temperature" equivalence principle. The effect of plasticizer content on the various mechanical properties and change rule of σm and εm were analyzed, showing that a good correlation between σm, εm, aK at low temperature and plasticizer content. The plasticizer content reducing, C1g increasing, "free volume of side group of NC molecule" decreasing make the mechanical performances (σm and εm) worsen.

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肖玮,李亮亮,王江宁,等. DNTF/RDX-CMDB推进剂低温力学性能[J].含能材料,2013,21(4):495-499.
XIAO Wei, LI Liang-liang, WANG Jiang-ning, et al. Mechanical Properties for DNTF/RDX-CMDB Propellants at Low Temperature[J]. Chinese Journal of Energetic Materials,2013,21(4):495-499.

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History
  • Received:September 24,2012
  • Revised:November 14,2012
  • Adopted:January 09,2013
  • Online: August 29,2013
  • Published: