CHINESE JOURNAL OF ENERGETIC MATERIALS
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Preparation and Properties of Lowest Eutectic Mixture TNAZ/ ANTA
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Science China Press,Institute of Chemical Engineering and Material,CAEP,Institute of Chemical Engineering and Material,CAEP,Institute of Chemical Engineering and Material,CAEP,Institute of Chemical Engineering and Material,CAEP,Institute of Chemical Engineering and Material,CAEP,School of Chemical Engineering Environment,Beijing Institute of Technology

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    Abstract:

    A phase diagram of 1,3,3-trinitroazetidine(TNAZ) and 3-amino-2,4,6-trinitroanisole (ANTA) was draw by origin software and the sensitivity, thermal stability, and detonation performance of the eutectic mixture were tested in order to design a potential TNT replacement for melt-cast explosive. The results show that when the weight percent of 3-methoxy-2,4,6-trinitrobenzenamine is 40%, the mixture has the lowest melting point, 84 ℃. The eutectic mixture has good thermal stability and its friction sensitivity, impact sensitivity, electrostatics sensitivity are comparable to TNT. The working capability of the mixture is 148% equivalent to TNT and 114% equivalent to Comp.B. Furthermore, another advantage of eutectic mixture is that there is no permeability oil at 70 ℃ for 6 h. These results indicate that the eutectic mixture is a potential replacement of TNT for melt-cast explosive. 

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张学梅,董海山,孙杰,等. TNAZ/ANTA最低共熔物的制备与性能[J].含能材料,2012,20(5):555-559.
ZHANG Xue-mei, DONG Hai-shan, SUN Jie, et al. Preparation and Properties of Lowest Eutectic Mixture TNAZ/ ANTA[J]. Chinese Journal of Energetic Materials,2012,20(5):555-559.

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History
  • Received:August 17,2012
  • Revised:August 27,2012
  • Adopted:September 04,2012
  • Online: September 26,2012
  • Published: