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Influence of Crystal Preferred Orientation on Thermal Expansion of Die Pressed TATB Based PBXs
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Institution of Chemical Materials, CAEP,Institution of Chemical Materials, CAEP,Institution of Chemical Materials, CAEP,Institution of Chemical Materials, CAEP,Institution of Chemical Materials, CAEP

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    Abstract:

    Thermal expansion of explosives have important impact on their applications and investigations on the relationship between thermal expansion and crystal preferred orientation can provide some guide for controlling the shape stability. This paper studied the preferred orientation (F) of 1,3,5-triamino-2,4,6-trinitrobenzene(TATB)crystals using X-ray diffraction and Rietveld refinement, and studied the thermal expansion of die-pressed cylinders with near-spherical, platy and raw materials TATB. Finally, the relationship between the crystals preferred orientation and thermal expansion was investigated. It′s shown that die-pressed TATB cylinders usually take place anisotropic thermal expansion with the coefficient of thermal expansion (CTE) along the diameter about 2 times of that along the radial, and the formula can be pressed as αCTE=(7.08+10.37×F)×10-5K-1. The thermal expansion of TATB cylinders increase with the crystal preferred orientation, and TATB cylinders with different morphological crystals have different preferred orientation. So, we can try to control the preferred orientation by change the crystal morphology, further to restrain the anisotropy of thermal expansion, and finally to improve the shape stability of TATB cylinders. 

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孙杰,张浩斌,温茂萍,等.模压TATB基PBX炸药件晶体取向对膨胀特性的影响[J].含能材料,2012,20(5):545-550.
SUN Jie, ZHANG Hao-bin, WEN Mao-ping, et al. Influence of Crystal Preferred Orientation on Thermal Expansion of Die Pressed TATB Based PBXs[J]. Chinese Journal of Energetic Materials,2012,20(5):545-550.

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History
  • Received:July 02,2012
  • Revised:August 14,2012
  • Adopted:August 15,2012
  • Online: September 26,2012
  • Published: