In order to improve the stability of unstable compound 1-amino-1-hydrazine-2, 2-dinitroethylene(AHDNE), the inclusion of AHDNE was studied. The presence of inclusion interactions of host compounds p-tertbutyl(p-nitro)calix[n]arenes(n = 4, 6, 8), β-cyclodextrin (β-CD) and β-cyclodextrin nitrate (β-NCD) with AHDNE was demostrated by UV-vis absorption spectra. The stoichiometric ratio and stability constants of the inclusion complexes were determined. The results show that the inclusion ratio is 1:1 and the stability constants of the inclusion compounds derived from the p-nitrocalix[n]arenes and β-NCD are ten times higher than those of their unnitrated precursors. The stability constants of the inclusion complexes coming from both p-nitrocalix[6]arene and β-NCD reach above 2×10⁴. XRD analyses of host -guest compound, inclusion complex and physical mixture confirmed the formation of inclusion complexes. The sensitivities of β-NCD/AHDNE inclusion complex are lower than those of AHDNE and β-NCD.