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THE THERMAL SAFETY AND A DENSITY FUNCTIONAL THEORETICAL STUDY ON N, N’-BIS[N-(2,2,2-TRINITROETHYL) -N-NITRO]ETHYLENEDIAMINE (BTNEDA)
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Xi’an Modern Chemistry Research Institute,Xi’an,Shaanxi,Xi’an Modern Chemistry Research Institute,Xi’an,Shaanxi,Xi’an Modern Chemistry Research Institute,Xi’an,Shaanxi,College of Chemical Engineering,Northwest University,Xi’an,Department of Mathematics/Institute of data analysis and computation chemistry,Northwest University,Xi’an,College of Chemical Engineering,Northwest University,Xi’an,College of Communication Scienceand Engineering,Northwest University,Xi’an,Xi’an Modern Chemistry Research Institute,Xi’an,Shaanxi

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    Abstract:

    With the help of the constant-volume standard combustion heat ( ) of N, N’-bis[N-(2,2,2-trinitroethyl) -N-nitro]ethylene diamine (BTNEDA), the initial temperature ( ), at which DSC curves deviates from the baseline, the onset temperature ( ) and maximum peak temperature ( ) from the non-isothermal DSC curves at different heating rates( ), the thermal decomposition activation energy( and ) and pre-exponential constant( ) obtained by Kissinger’s method and Ozawa’s method, the value of from equation and the value of from equation , the value of b from equation

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胡荣祖,赵凤起,高红旭,等. N, N’-二[ (2,2,2-三硝基乙基-N-硝基)乙二胺的热安全性和密度泛函理论研究(英)[J].含能材料,2012,20(5):505-513.
HU Rong-zu, ZHAO Feng-qi, GAO Hong-xu, et al. THE THERMAL SAFETY AND A DENSITY FUNCTIONAL THEORETICAL STUDY ON N, N’-BIS[N-(2,2,2-TRINITROETHYL) -N-NITRO]ETHYLENEDIAMINE (BTNEDA)[J]. Chinese Journal of Energetic Materials,2012,20(5):505-513.

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History
  • Received:May 21,2012
  • Revised:June 25,2012
  • Adopted:
  • Online: September 25,2012
  • Published: