Synthesis and Characterization of Glycidyl Nitrate
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The synthetic route of glycidyl nitrate(GN) was improved. Glycidol was synthesized by the cyclization process from allyl alcohol and m-CPBA, then glycidyl nitrate was synthesized with glycidol as raw materials and HNO3/(AcO) 2O as nitrating agent. Results show that the yield of GN is 70.2%, and after vacuum distillation, the purity of GN is 98.9%. The product was characterized by IR, 1H NMR and elemental analysis. The optimal nitration conditions are as follows: the molar ratio of HNO3/GA is 1.5:1.0, reaction temperature is -10 ℃, and reaction is quenched when addition is finished.
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莫洪昌,甘孝贤,卢先明,等.缩水甘油醚硝酸酯的合成及表征[J].含能材料,2009,17(4):396-398. MO Hong-chang, GAN Xiao-xian, LU Xian-ming, et al. Synthesis and Characterization of Glycidyl Nitrate[J]. Chinese Journal of Energetic Materials,2009,17(4):396-398.