Six nitro fulleropyrrolidine derivatives were synthesized by the 1，3-dipolar cycloaddition reactions of ［60］fullerene and the nucleophilic substitution reaction of N-unsubstituted fulleropyrrolidine. The structures of the products were characterized by ultraviolet-visible spectroscopy(UV-Vis)，Fourier transform infrared spectrometer(FT-IR)，mass spectrometry(MS) and ¹H，¹³C nuclear magnetic resonance(NMR) techniques. The effects of the different products on the impact sensitivity and friction sensitivity of HMX were tested. The friction and impact sensitivities of HMX reduces from 100% to 48% and to 50%，respectively when 1% N-methyl-2-(3-nitrophenyl)fulleropyrrolidine 2 added in HMX.