Differential and Integral Isoconversional Non-linear Methods and their Application in Physical Chemistry Study of Energetic Materials Ⅴ. Theory and Numerical Method Based on Kooij′s Formula

Home > Archive>Volume 16, Issue 3, 2008 >290-294

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HU Rong-zu
HU Rong-zu
Xi′an Modern Chemistry Research Institute, Xi′an 710065, China；
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ZHAO Feng-qi
ZHAO Feng-qi
Xi′an Modern Chemistry Research Institute, Xi′an 710065, China；
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GAO Hong-xu
GAO Hong-xu
Xi′an Modern Chemistry Research Institute, Xi′an 710065, China；
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ZHANG Hai
ZHANG Hai
Department of Mathematics, Northwest University, Xi′an 710069, China；
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ZHAO Hong-an
ZHAO Hong-an
College of Communication Science and Engineering, Northwest University, Xi′an 710069, China；
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MA Hai-xia
MA Hai-xia
College of Chemical Engineering, Northwest University, Xi′an 710069, China
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Abstract:

Eight typical differential and integral isoconversional non-linear equations based on Kooij′s formula for computing the apparent activation energy (Ｅ_α) from isothermal and non-isothermal data were derived. The numerical methods of computing the value of Ｅ_α of decomposition reaction of energetic materials via the equations were presented.

Key words:physical chemistry; energetic materials; differential isoconversional non-linear method; integral isoconversional non-linear method; decomposition reaction; apparent activation energy

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胡荣祖,赵凤起,高红旭,等.非线性等转化率的微、积分法及其在含能材料物理化学研究中的应用Ⅴ. 基于Kooij公式的理论和数值方法[J].含能材料,2008,16(3):290-294.
HU Rong-zu, ZHAO Feng-qi, GAO Hong-xu, et al. Differential and Integral Isoconversional Non-linear Methods and their Application in Physical Chemistry Study of Energetic Materials Ⅴ. Theory and Numerical Method Based on Kooij′s Formula[J]. Chinese Journal of Energetic Materials,2008,16(3):290-294.

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Received:December 18,2007
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Online: May 06,2011
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