The compatibilities of ammonium dinitramide (ADN) with five kinds of the binders including hydroxyl terminated polybutadiene (HTPB),3,3-azidomethyl-3-methyloxetane-tetrahydrafuran (BAMO-THF),nitroglycerine/nitrocellulose (NG+NC),polyethylene glycol (PEG) and poly(epoxy ethane tertrahydrafuran) (PET),were studied by vacuum stability test (VST). Meanwhile the compatibilities of ADN with three kinds of the binders were studied by DSC and LAWA techniques. The results show that the systems of PEG and (NG+NC) with ADN have strong reactivity and is rated to be incompatible using three methods. The system of PET with ADN is judged to be incompatible by VST,while to be compatible by DSC and LAWA. The reasons causing different conclusion from different methods were discussed.