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RDX Coated with Hyantoin/Triazines Composite Bonding Agent
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    Abstract:

    RDX was coated with hyantoin/triazines composite bonding agent and the effects of the processing parameters,including reaction time, reaction temperature and bonding agent mass on the coating degree were studied by means of water-solution suspending method in the L9(34) orthogonal experiment. The coated RDX was characterized by X-ray photoelectron spectroscopy(XPS), scanning electron microscope(SEM), Fourier transform infrared spectroscopy(FTIR), differential scanning calorimetry(DSC) and impact sensitivity (H50). The optimum conditions are as follows: 10.0 g RDX, reaction time 90 min,reaction temperature 50 ℃, 0.3 g composite bonding agent (CBA), and stirring speed 700 r·min-1. Accordingly,coating degree is up to 87%. It is found that surface of the coated RDX is covered by clear film with a thickness of about 0.2 μm. In FTIR spectra, NO2 group absorption peak has a 22 cm-1 red shift to 1510 cm-1and the absorption band widened. Thermal decomposition peak temperature is enhanced 0.4 ℃. The characteristic height of impact sensitivity (H50) is increased by 4.5 cm.

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李江存,焦清介,任慧,等.海因/三嗪类复合键合剂包覆黑索今的研究[J].含能材料,2008,16(1):56-59.
LI Jiang-cun, JIAO Qing-jie, REN Hui, et al. RDX Coated with Hyantoin/Triazines Composite Bonding Agent[J]. Chinese Journal of Energetic Materials,2008,16(1):56-59.

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History
  • Received:May 31,2007
  • Revised:
  • Adopted:
  • Online: May 06,2011
  • Published: