3,6-Dihydrazine-1,2,4,5-tetrazine and its energetic salts were synthesized from the easily available starting materials like triaminoguanidine and 2,4-penatanedione. The synthesis route in literature was magnified properly. Moreover, the synthesized compounds were characterized by spectra analysis(IR, NMR, EA and MS) and the explosive properties (impact and friction sensitivity) and thermal properties (TGA/DTG) were studied.