A new energetic material compound 3-amino-4-aminoximinofurazan(AAOF) with yield of 72.4% was synthesized by using dicyanopropane as initial material through 4-step continuous reaction by one-pot method. Its molecular structure was characterized by IR,MS,¹H-NMR,¹³C-NMR,elemental analysis and UV. A 500 gram-grade synthesis procedure of 3-amino-4-aminoximinofurazan (AAOF) was realized on the basis of the optimized procedure. The synthesis reaction mechanism of AAOF was theoretically deduced and validated .