CHINESE JOURNAL OF ENERGETIC MATERIALS
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One-pot Synthesis of Glycidyl Nitrate
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    Abstract:

    A mild, low cost synthetic method of glycidyl nitrate is developed via so called one-pot procedure. Epichlorohydrin added dropwise to the dilute nitric acid (35 wt%) resulted in ring-opening reaction at about 20 ℃. Ring-closing occurred then by the addition of aqueous sodium hydroxide. Glycidyl nitrate was obtained in moderate yield (60%) and its structure was characterized by Fourier transform infrared spectroscopy, hydrogen and carbon nuclear magnetic resonance and elemental analysis.

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邱少君,甘孝贤,樊慧庆.缩水甘油硝酸酯的一锅法合成(英)[J].含能材料,2005,13(4):211-213.
QIU Shao-jun, GAN Xiao-xian, FAN Hui-qing. One-pot Synthesis of Glycidyl Nitrate[J]. Chinese Journal of Energetic Materials,2005,13(4):211-213.

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History
  • Received:January 18,2005
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  • Online: November 03,2011
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