CHINESE JOURNAL OF ENERGETIC MATERIALS
+Advanced Search

Synthesis and Properties of 3,6-bis(1H-1,2,3,4-tetrazol-5-yl-amino)-1,2,4,5-tetrazine
Author:
Affiliation:

Fund Project:

  • Article
  • |
  • Figures
  • |
  • Metrics
  • |
  • Reference
  • |
  • Related
  • |
  • Cited by
  • |
  • Materials
    Abstract:

    An insensitive explosive with high nitrogen content and high standard enthalpy of formation,3,6-bis(1H-1,2,3,4-tetrazol-5-yl-amino)-1,2,4,5-tetrazine was synthesized using triaminoguanidine nitrate and 5-aminotetraazole as starting materials. This synthesis is a four-step process,including cyclization,oxidation and dehydrogenation followed by nuclcophilic substitution. The structure of the obtained compound has been identified by IR,1H NMR and 13C NMR spectra,and element analysis. Some important properties of BTATz have been determined and are as follows: density of 1.76 g·cm-3,melting point of 264~285 ℃,detonation velocity of 7 520 m·s-1,combustion velocity of 5.6 mm·s-1(101 kPa),pressure exponent 0.49,exothermic peak temperature of 320 ℃(DSC method). It is expected that BTATz might be promising in applying to insensitive explosives and low signature propellants.

    Reference
    Related
    Cited by
Article Metrics
  • PDF:
  • HTML:
  • Abstract:
  • Cited by:
Get Citation

岳守体,阳世清.3,6-双(1-氢-1,2,3,4-四唑-5-氨基)-1,2,4,5-四嗪的合成及其性能[J].含能材料,2004,12(3):155-157.
YUE Shou-ti, YANG Shi-qing. Synthesis and Properties of 3,6-bis(1H-1,2,3,4-tetrazol-5-yl-amino)-1,2,4,5-tetrazine[J]. Chinese Journal of Energetic Materials,2004,12(3):155-157.

Cope
History
  • Received:September 10,2003
  • Revised:
  • Adopted:
  • Online: November 03,2011
  • Published: