Synthesis and Properties of N,N′-Di(nitrofurazano)oxalamide
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N,N′-di(nitrofurazano)oxalamide (DNFOA) was synthesized from 3,4-diaminofurazan by acidylating. The structure of DNFOA has been identified by IR,1HNMR,MS and elemental analysis. The density of DNFOA was determined to be 1.90 g·cm-3 by suspension method. The values of the standard enthalpy,the detonation velocity and the explosive pressure at C-J point were calculated to be 303.6 kJ·mol-1,8 559.6 m·s-1,33.6 GPa, respectively. As a low-sensitivity high energetic density compound,the impact-sensitivity (H50) of DNFOA was mensurated to be 82 cm(5 kg drop hammer).
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李战雄,欧育湘,陈博仁. N, N′-二(硝基呋咱基)草酰胺的合成及性能[J].含能材料,2002,10(1):10-12. LI Zhan-xiong, OU Yu-xiang, CHEN Bo-ren. Synthesis and Properties of N, N′-Di(nitrofurazano)oxalamide[J]. Chinese Journal of Energetic Materials,2002,10(1):10-12.