A TREATMENT METHOD OF NON-ISOTHERMAL REACTION KINETCS FOR ENERGETIC MATERIALS
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Two-point method was established to determine the non-isothermal reaction kinetic parameters of energetic materials by using four parameters from two characteristic points on the non-isothermaI DSC curve. Two peak indexes Hw and τw were defined to judge the non-isothermaI DSC curve of energetic materials.It was found that only when these indexes coincided with the conditions of 0.1≤Hw≤1.0 and 1.8×1O-2≤τm≤9.8× 1O-2,the peak could be treated with kinetics methods. Some empiric judgements were given for chosen the most probable mechanism function and the reasonable kinetics parameters.A typical computation example was listed to compare the two-point method with those commonly used in kinetics.
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张同来,胡荣祖,李福平.含能材料的一种非等温反应动力学处理方法[J].含能材料,1994,2(2):19-25. Zhang Tong-lai, Hu Rong-zu, Li Fu-ping. A TREATMENT METHOD OF NON-ISOTHERMAL REACTION KINETCS FOR ENERGETIC MATERIALS[J]. Chinese Journal of Energetic Materials,1994,2(2):19-25.