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石墨对TATB基PBX导热性能的影响
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(中国工程物理研究院化工材料研究所, 四川 绵阳 621999)

作者简介:

林聪妹(1985-),女,助理研究员,主要从事高聚物粘结炸药的配方设计和性能研究。e-mail: lincmei2009@163.com 通信联系人: 刘世俊(1975-),男,副研究员,主要从事含能材料设计及性能研究。e-mail: lsj99@sohu.com

通讯作者:

刘世俊(1975-),男,副研究员,主要从事含能材料设计及性能研究。e-mail: lsj99@sohu.com

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Effect of Graphite on Thermal Conduction Properties of TATB-based Polymer Bonded Explosives
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(Institute of Chemical Materials, CAEP, Mianyang 621999, China)

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    摘要:

    为有效调节TATB基高聚物粘结炸药(PBX)的导热性能, 利用闪光导热仪研究了石墨包覆方式(内包和外包)、温度及石墨含量对TATB基PBX导热系数的影响, 应用Agari模型分析了TATB基PBX的导热机制。结果表明, 添加高导热石墨可改善TATB基PBX的导热性能。常温下, 由内包和外包1%(质量分数)石墨改性的TATB基PBX配方的导热系数分别为0.572 W·(m·K)-1和0.697 W·(m·K)-1, 显示, 外包石墨包覆方式比内包石墨包覆方式更好。与不含石墨的TATB基PBX相比, 内包1%和外包1%石墨的TATB基PBX的导热性能分别提高4.76%和27.66%。随温度升高, TATB基PBX及其石墨改性配方的导热性能逐渐降低。随着石墨含量增加, 外包石墨改性的TATB基PBX的导热性能升高。外包2%(质量分数)石墨可使TATB基PBX的导热系数提高至0.786 W·(m·K)-1。TATB基PBX及由内包石墨改性的配方的导热机制符合串联模型, 而由外包石墨改性的配方的导热机制介于串联模型和并联模型之间。

    Abstract:

    To regulate the thermal conduction performance of TATB-based polymer bonded explosive(PBX), the effects of graphite coating way(inner-coating and outer-coating), temperature and graphite content on the thermal conductivity of TATB-based PBX were investigated by a laser thermal conductivity apparatus.The thermal conduction mechanism of TATB-based PBX was analyzed by Agari model.Results show that the addition of graphite with high thermal conduction performance can improve the thermal conduction performances of TATB-based PBXs under room temperature, and the thermal conductivities of TATB-based PBXs with 1%(mass fraction) inner-coating and 1% outer-coating graphite are 0.572 W·(m·K)-1and 0.697 W·(m·K)-1, respectively, revealing that the outer-coating graphite way is better than inner-coating.Compared with the TATB-based PBX without graphite, thermal conductivities of TATB-based PBXs with 1% inner-coating graphite and 1% outer-coating graphite increase by 4.76% and 27.66%, respectively.With the increasing of temperature, the thermal conductivities of TATB-based PBX and its formulations modified with graphite gradually decrease.With increasing the graphite content, thermal conduction performances of TATB-based PBXs modified with outer-coating graphite increase.The 2%(mass fraction) outer-coating graphite can make the thermal conductivity of TATB-based PBX increase to 0.786 W·(m·K)-1.The thermal conduction mechanism of TATB-based PBX and formulation modified with inner-coating graphite accords with the series model, whereas the thermal conduction mechanism of formulation modified with outer-coating graphite is between series model and parallel model.

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引用本文

林聪妹,刘佳辉,何冠松,等.石墨对TATB基PBX导热性能的影响[J].含能材料, 2015, 23(11):1119-1123. DOI:10.11943/j. issn.1006-9941.2015.11.016.
LIN Cong-mei, LIU Jia-hui, HE Guan-song, et al. Effect of Graphite on Thermal Conduction Properties of TATB-based Polymer Bonded Explosives[J]. Chinese Journal of Energetic Materials, 2015, 23(11):1119-1123. DOI:10.11943/j. issn.1006-9941.2015.11.016.

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  • 收稿日期: 2014-09-04
  • 最后修改日期: 2014-12-26
  • 录用日期: 2015-01-04
  • 在线发布日期: 2015-10-19
  • 出版日期: 2015-10-28