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含能低共熔物熔铸载体炸药的研究进展
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西南科技大学材料与化学学院环境友好能源材料国家重点实验室, 四川 绵阳 621010

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国家自然科学基金(22575203),四川省科技计划青年科技创新研究团队项目(2026NSFSCZY0069),四川省自然科学基金重点项目(2025ZNSFSC0036),西南科技大学科研基金资助(25zx7112)


Research Progress on Energetic Eutectic Mixtures as Melt-Cast Carrier Explosives
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State Key Laboratory of Environment-Friendly Energy Materials,School of Materials and Chemistry,Southwest University of Science and Technology,Mianyang 621010, China

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    摘要:

    熔铸载体炸药是熔铸炸药体系中不可或缺的低熔点组分,其性能直接决定熔铸炸药的工程应用效果。针对传统熔铸载体炸药2,4,6-三硝基甲苯(TNT)应用存在的固有局限,含能低共熔物凭借热化学性质、安全性和能量性能可调控的优势,成为了当前含能材料领域的研究热点。本文系统阐述了含能低共熔物T-X相图、H-X相图的构建方法,梳理了利用相图获取最低共熔物组成配比、低共熔温度及相态分布特征的技术路径,分类总结了1,3,3-三硝基氮杂环丁烷(TNAZ)、3,4‐二硝基呋咱基氧化呋咱(DNTF)、1-甲基-3,4,5-三硝基吡唑(MTNP)等系列典型含能低共熔物的最新研究成果。结合目前领域内的研究现状,对含能低共熔物后续研发重点与应用前景进行展望,可为新型低感高能熔铸载体炸药的设计与配方优化提供参考。

    Abstract:

    Melt-cast carrier explosives are fundamental low-melting-point constituents for melt-cast explosive formulations, and their properties are critical to the engineering practicability of melt-cast explosives. To address the inherent drawbacks of the traditional melt-cast carrier explosive 2,4,6-trinitrotoluene (TNT), energetic eutectic mixtures have emerged as a popular research focus, benefiting from their tunable thermochemical properties, energy and safety performances. Methods for constructing T-X and H-X phase diagrams of energetic eutectic mixtures are elaborated, alongside approaches to determine their compositions, melting points and phase distribution rules. Additionally, the state-of-the-art studies on energetic eutectic mixtures based on 1,3,3-trinitroazetidine (TNAZ), 3,4-dinitrofurzanfuroxan (DNTF), 1-methyl-3,4,5-trinitropyrazole (MTNP) are discussed. On the basis of current research situation, the development potential and core research directions of energetic eutectic mixtures are proposed. This work intends to facilitate the design and formula optimization of novel low-sensitivity, high-energy melt-cast explosives.

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王滨燊,金波,彭汝芳.含能低共熔物熔铸载体炸药的研究进展[J].含能材料, 2026, 34(9):1068-1079. DOI:10.11943/CJEM2026148.
WANG Binshen, JIN Bo, PENG Rufang. Research Progress on Energetic Eutectic Mixtures as Melt-Cast Carrier Explosives[J]. Chinese Journal of Energetic Materials, 2026, 34(9):1068-1079. DOI:10.11943/CJEM2026148.

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历史
  • 收稿日期: 2026-06-24
  • 最后修改日期: 2026-09-07
  • 录用日期: 2026-08-24
  • 在线发布日期: 2026-09-02
  • 出版日期: 2026-09-25