CHINESE JOURNAL OF ENERGETIC MATERIALS
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芳酰腙类小分子凝胶剂的合成及其凝胶燃料多维性能评价体系构建
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北京理工大学化学与化工学院

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国家自然科学基金(22105024)


Development and Multidimensional Evaluation Framework of Aroylhydrazone-Based Gel Fuels
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Beijing Institute of Technology, School of Chemistry and Chemical Engineering

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    摘要:

    为探究小分子凝胶剂对凝胶燃料综合性能的影响,设计并合成了5种芳酰腙类小分子凝胶剂,采用加热-冷却法制备煤油凝胶燃料,研究其成胶机理,并从凝胶剂最小添加量(A),凝胶燃料相变温度(Tg)、物理化学稳定性(Spc)、能量密度损耗率(Eloss)、剪切变稀能力(Sthin)以及复凝性(R)6个维度构建了凝胶剂性能综合评价体系。结果显示,凝胶剂均能通过氢键、π-π共轭等非共价作用形成三维网络结构,有效束缚煤油分子,其凝胶燃料表现出热可逆性(Tg=50~80 ℃),并具备良好的物理化学稳定性与剪切变稀行为。其中,L18凝胶剂的最小添加量最低(3.1%),成胶速度最快(15 s);L5凝胶剂的物理化学稳定性最佳,在10000 r·min-1高离心速率下的质量保留率高达97.5%;L16凝胶剂的剪切变稀能力最强,剪切后的黏度仅为34.72 mPa·s。基于建立的多维性能评价体系,L16和L18凝胶剂展现出显著的综合优势。

    Abstract:

    To investigate the effect of low-molecule-weight gelators on the overall performance of gel fuels, five acylhydrazone-based low-molecular-weight gelators were designed and synthesized. Kerosene gel fuels were prepared using the heating-cooling method, and the gelation mechanism was examined. A comprehensive evaluation system for gelator performance was established based on six parameters: the minimum addition amount of gelators (A), the phase transition temperature (Tg), the physicochemical stability (Spc), the loss rate of energy density (Eloss), the shear thinning capacity (Sthin) and the resetting property (R). The results showed that all gelators could form three-dimensional network structures through non-covalent interactions such as hydrogen bonds and π-π conjugation, effectively confining kerosene molecules. Their gel fuels exhibited thermal reversibility (Tg = 50-80 ℃) and had good physical and chemical stability and shear thinning behavior. Among them, L18 gelator had the lowest minimum addition amount (3.1%) and the fastest gelation speed (15 s). L5 gelator had the best physical and chemical stability and the mass retention rate was 97.5% at a high centrifugal speed of 10000 r·min-1. L16 gelator had the strongest shear thinning ability, with a viscosity of only 34.72 mPa·s after shearing. The conclusion indicated that based on the multi-dimensional performance evaluation system established by the institute, L16 and L18 gelators demonstrated significant comprehensive advantages.

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柳金茗,赵鑫,李伟,等. 芳酰腙类小分子凝胶剂的合成及其凝胶燃料多维性能评价体系构建[J]. 含能材料,DOI:10.11943/CJEM2026002.

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  • 收稿日期: 2025-12-31
  • 最后修改日期: 2026-03-20
  • 录用日期: 2026-03-08
  • 在线发布日期: 2026-03-17
  • 出版日期: