CHINESE JOURNAL OF ENERGETIC MATERIALS
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含能材料包覆降感研究进展
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中国人民解放军军事科学院防化研究院

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基金项目:

国家自然科学基金(51404279)


Progress in Desensitization of Energetic Materials via Encapsulation
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Chemical Defense Institute, Academy of Military Sciences

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Grant support: National Natural Science Foundation of China(No. 51404279)

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    摘要:

    含能材料的机械感度严重制约其安全应用,如何在保障高能量密度的同时实现低感度,是当前含能材料研究的核心难题。本文聚焦于含能材料表面包覆降感技术,综述了近年来主流的包覆技术与材料体系的研究进展。重点剖析了包覆层通过“填充与缓冲”、“能量吸收与隔绝”及“润滑作用”三大机制抑制“热点”形成与传播原理;归纳了水悬浮、乳液包覆法、原位聚合、喷雾法、微流控等关键技术的特点与适用性;全面评述了高分子黏合剂、碳材料、蜡类、含能材料、盐类、仿生材料及复合材料等七类包覆体系的降感效果与机制差异。通过评估不同包覆体系的综合性能与发展潜力,指出未来研究应聚焦于降感机理的深层揭示、包覆结构的智能化设计、工艺过程的精准控制以及多功能一体化新材料的创制,以推动工艺创新、过程精准控制、新材料体系创制与功能集成,全面提升含能材料能量与安全性的协同性。

    Abstract:

    The mechanical sensitivity of energetic materials severely restricts their safe application. How to achieve low sensitivity while ensuring high energy density remains the core challenge in current energetic materials research. This paper focuses on the surface coating desensitization technology for energetic materials and reviews recent research progress of mainstream coating technologies and material systems. It emphasizes the analysis of the principles by which the coating layer inhibits the formation and propagation of “hot spots” during mechanical stimulation through three major mechanisms: “filling and buffering”, “energy absorption and isolation”, and “lubrication”. The characteristics and applicability of key technologies such as water suspension, emulsion suspension, in-situ polymerization, spray and microfluidics are summarized. A comprehensive review is conducted on the desensitization effects and mechanism differences of seven types of coating systems, including polymer adhesives, carbon materials, waxes, energetic materials, salts, biomimetic materials, and composite materials. By evaluating the overall performance and development potential of different coating systems, it is suggested that future research should focus on the in-depth revelation of desensitization mechanisms, intelligent design of coating structures, precise process control, and the creation of new multifunctional integrated materials. These efforts are directed toward driving technological innovation, facilitating the development new material systems, and ultimately enhancing the synergy between energy density and safety of energetic materials.

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引用本文

张艺,于志宏,徐菡卿,等.含能材料包覆降感研究进展[J].含能材料, 2026, 34(2):180-197. DOI:10.11943/CJEM2025260.
ZHANG Yi, YU Zhi-hong, XU Han-qing, et al. Progress in Desensitization of Energetic Materials via Encapsulation[J]. Chinese Journal of Energetic Materials, 2026, 34(2):180-197. DOI:10.11943/CJEM2025260.

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历史
  • 收稿日期: 2025-12-11
  • 最后修改日期: 2026-01-15
  • 录用日期: 2026-02-02
  • 在线发布日期: 2026-02-07
  • 出版日期: