CHINESE JOURNAL OF ENERGETIC MATERIALS
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BTF/NC/GAP含能复合物的制备及微尺寸传爆性能研究
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作者单位:

1.中北大学环境与安全工程学院,山西 太原 030051;2.中国工程物理研究院流体物理研究所,四川 绵阳 621900;3.山西江阳化工有限公司,山西 太原 030051;4.驻太原地区第三军事代表室,山西 太原 030051

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基金项目:

国家自然科学基金(22105184)


Preparation and Micro-scale Detonation Propagation Performance of BTF/NC/GAP Energetic Composites
Author:
Affiliation:

1.School of Environment and Safety Engineering, North University of China,Taiyuan 030051, China;2.Institute of Fluid Physics, CAEP, Mianyang 621900, China;3.Shanxi Jiangyang Chemical Co., Ltd., Taiyuan 030051, China;4.The third Military Representative Office in Taiyuan, Taiyuan 030051, China

Fund Project:

Grant support: National Natural Science Foundation of China (No. 22105184)

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    摘要:

    为扩展微传爆药剂的设计区间,选择具有低爆轰临界尺寸、类平面结构的苯并三氧化呋咱(BTF)为主体炸药、硝化棉(NC)和聚叠氮缩水甘油醚(GAP)为黏结剂、乙酸乙酯为溶剂,配制出4种BTF基全液式炸药油墨,利用喷墨打印技术平台构筑出BTF/NC/GAP含能复合物,探究了BTF/NC/GAP含能复合物的微观结构、爆轰临界尺寸和传爆性能等。结果表明,BTF/NC/GAP含能复合物中主体炸药以类片状结构存在,尺寸主要处于1~10 μm;BTF/NC/GAP含能复合物具有较好的能量存储特性和微尺寸传爆能力,其能量水平达到理论值的90%以上,爆轰临界尺寸最低可达1 mm×0.102 mm(2%NC/GAP含量),爆速最高可达8436 m·s-1(5%NC/GAP含量)。同时,NC/GAP的含量增长导致BTF/NC/GAP含能复合物出现纳米孔洞向微米孔洞的迁移,进一步提高了热点形成几率并增强了能量释放效率,当NC/GAP含量为10%时,含能复合物的实测爆速值与理论爆速值的比值最高(94.61%),拥有更佳的能量释放特征和传爆稳定性。

    Abstract:

    To expand the design range of micro-booster explosives, four fully liquid explosive inks were formulated by using benzotrifuroxan (BTF) as the main explosive with low detonation critical size characteristics and planar-like structure, nitrocellulose (NC) and glycidyl azide polymer (GAP) as binders, and ethyl acetate as the solvent. The BTF/NC/GAP energetic composites were constructed using inkjet printing technology. The microstructure, critical size of detonation, and detonation propagation performance of the composites were systematically investigated. Results show that the main explosives in BTF/NC/GAP composites exist in a flake-like structure with particle size mainly ranges from 1 to 10 μm. The composites have excellent energy storage properties and micro-scale detonation propagation capability, achieving over 90% of their theoretical energy output. The critical size of detonation reaches a minimum of 1 mm×0.102 mm (2% NC/GAP content), while the maximum detonation velocity attains 8436 m·s-1(5% NC/GAP content). Moreover, the increased NC/GAP content induces a transition from nano- to micro-scale pores within the composites, enhancing the probability of hotspot formation and improving the efficiency of energy release. At 10% NC/GAP content, the ratio of experimental to theoretical detonation velocity peaks at 94.61%, demonstrating more complete energy release characteristics and stable detonation propagation.

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引用本文

徐传豪,陈森,程王健,等. BTF/NC/GAP含能复合物的制备及微尺寸传爆性能研究[J].含能材料, 2025, 33(12):1405-1415. DOI:10.11943/CJEM2025200.
XU Chuan-hao, CHEN Sen, CHENG Wang-jian, et al. Preparation and Micro-scale Detonation Propagation Performance of BTF/NC/GAP Energetic Composites[J]. Chinese Journal of Energetic Materials, 2025, 33(12):1405-1415. DOI:10.11943/CJEM2025200.

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  • 收稿日期: 2025-09-15
  • 最后修改日期: 2025-11-17
  • 录用日期: 2025-11-10
  • 在线发布日期: 2025-11-17
  • 出版日期: 2025-12-25