CHINESE JOURNAL OF ENERGETIC MATERIALS
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基于丁羟推进剂的双组分药浆的静态混合法制备
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1.南京理工大学化学与化工学院, 江苏 南京 210094;2.上海航天动力技术研究所, 浙江 湖州 313000;3.西安北方惠安化学工业有限公司, 陕西 西安 710302

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Preparation of HTPB Propellant by Mixing Two-Component Slurry with a Static Mixer
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1.School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094;2.Shanghai Space Propulsion Technology Research Institute, Huzhou, 313000;3.Xi'an North Huian Chemical Industry Co. Ltd, Xi'an 710302

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    摘要:

    传统一锅法制备丁羟推进剂时药浆混合工艺中存在制量大和药浆适用期的问题,为此,研究设计开发了静态混合器混合工艺,将预制黏合剂药浆和固化剂药浆分别储存于料筒,螺杆泵计量后挤入静态混合器进行混合、浇注。采用计算流体动力学(CFD)模拟得到入口压力为5×105 Pa,出口压力为大气压时双组分药浆在静态混合器中的混合过程云图;设计了适用于静态混合器混合工艺的双组分固化体系;并基于该固化体系,以K₂SO₄、CaCO3为氧化剂代料,通过静态混合器混合工艺制备了固含量达85%、未添加键合剂的氧化剂代料推进剂,对其微观形貌进行了表征并对其力学性能进行了测试。结果表明,静态混合器可将双组分药浆混合均匀;推进剂拉伸强度为0.4 MPa,断裂伸长率为37.5%,断面致密均匀、未见裂纹或空隙。静态混合器混合工艺在制量小、对药浆适用期无要求。

    Abstract:

    To address the issues of large in-process quantities and strict pot-life demands of slurry in traditional one-pot propellant slurry mixing, a static mixer mixing technique was designed and developed. In this technique, the pre-prepared binder slurry and curing agent slurry are stored separately in reservoirs, metered by screw pumps, extruded into a static mixer for blending, and then directly cast. Computational Fluid Dynamics (CFD) simulations were used to generate cloud images of the mixing process of a two-component slurry in a static mixer under typical conditions. A two-component curing system suitable for the static mixer mixing process was designed and synthesized. Based on this curing system, using K₂SO₄ and CaCO₃ as simulated oxidizers, a simulated oxidizer propellant with a solid content of 85% and without the addition of a bonding agent was prepared via the static mixer mixing process. The mechanical properties and microstructure of the propellant were characterized. Results indicate that the static mixer achieved homogeneous mixing of the two-component slurry. The resulting propellant exhibited a tensile strength of 0.4 MPa and an elongation at break of 37.5%, with a fracture surface that was dense and uniform, showing no cracks or voids. The static mixer mixing process offers advantages of small in-process quantity and no requirement for pot life of the slurry.

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引用本文

任丽媛,陈建发,徐纪琳,等.基于丁羟推进剂的双组分药浆的静态混合法制备[J].含能材料, 2025, 33(12):1385-1394. DOI:10.11943/CJEM2025176.
REN Li-yuan, CHEN Jian-fa, XU Ji-lin, et al. Preparation of HTPB Propellant by Mixing Two-Component Slurry with a Static Mixer[J]. Chinese Journal of Energetic Materials, 2025, 33(12):1385-1394. DOI:10.11943/CJEM2025176.

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历史
  • 收稿日期: 2025-08-11
  • 最后修改日期: 2025-11-18
  • 录用日期: 2025-11-17
  • 在线发布日期: 2025-11-17
  • 出版日期: 2025-12-25