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HTPB/AOT/AP自熄火固体推进剂燃烧性能及增压熄火机理
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1.西北工业大学;2.西安航天动力技术研究所

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Combustion Behavior and Pressurization-induced Extinguished Mechanism of HTPB/AOT/AP Self-extinguished Solid Propellant
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1.Northwestern Polytechnical University, National Key Laboratory of Solid Propulsion, Xi'an , China;2.Xi’an Aerospace Solid Propulsion Technology Institute, Xi’an , China

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    摘要:

    为研究自熄火固体推进剂燃烧性能并揭示增压熄火机理,使用丁二酸二辛酯磺酸钠(AOT)作为熄火控制剂制备了HTPB/AOT/AP自熄火固体推进剂,并对推进剂燃速、燃烧波结构、火焰形态和熄火燃面形貌等进行了实验表征。实验结果表明:AOT使推进剂在10 MPa以下的压强指数由0.37降低至-1.36,其中压强接近临界熄火压强时燃速由5.9 mm·s-1降低至2.9 mm·s-1,推进剂在压强增大至10 MPa时自熄火,压强更高时仍无法自持燃烧;压强接近临界熄火压强时,推进剂燃面上覆盖了厚度约230 μm的熔融层,降低了推进剂燃面温度和气相温度梯度,与2 MPa时相比,燃面温度由865 K降低至420 K,气相温度梯度由74.9 K·μm-1降低至0.19 K·μm-1;揭示了自熄火固体推进剂增压熄火机理,即AOT使推进剂表面覆盖较厚的熔融层,阻碍气相火焰对燃面的热反馈,降低燃面温度和凝聚相反应速率,最终导致推进剂无法自持燃烧而熄火。

    Abstract:

    To study the combustion performance of self-extinguishing solid propellants and the pressurization-induced extinguishing mechanism, HTPB/AOT/AP self-extinguished solid propellants were prepared by using sodium dioctyl sulfosuccinate (AOT) as extinguishing agent. Experimental characterizations of burning rate, combustion wave structure, flame morphology and flame quenching burning surface topography of the propellants were carried out. Results show that AOT reduces the pressure exponent of propellant below 10 MPa from 0.37 to -1.36, and the burning rate decreases from 5.9 mm·s-1 to 2.9 mm·s-1 as the pressure approaches the critical extinguished pressure. AOT causes the propellant to self-extinguish when the pressure increases to 10 MPa, with unsustainable combustion observed at higher pressures. As the pressure approaches the critical extinction pressure, a molten layer with a thickness of 230 μm covers the burning surface of propellant, reducing the burning surface temperature from 865 K to 420 K and the gaseous phase temperature gradient from 74.9 K·μm-1 to 0.19 K·μm-1 compared with that of pressure of 2 MPa. The pressurization-induced extinguishing mechanism of self-extinguishing solid propellant is revealed. AOT causes a thicker molten layer to cover the surface of propellant, obstructs the heat feedback from the gaseous flame to the burning surface, reduces the temperature of burning surface and the reaction rate of condensed phase, and ultimately results in extinguishment due to the failure to maintain self-sustained combustion.

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陈泽昕,刘林林,杨玉新,等. HTPB/AOT/AP自熄火固体推进剂燃烧性能及增压熄火机理[J].含能材料, 2025, 33(8):898-906. DOI:10.11943/CJEM2025140.
CHEN Ze-xin, LIU Lin-lin, YANG Yu-xin, et al. Combustion Behavior and Pressurization-induced Extinguished Mechanism of HTPB/AOT/AP Self-extinguished Solid Propellant[J]. Chinese Journal of Energetic Materials, 2025, 33(8):898-906. DOI:10.11943/CJEM2025140.

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  • 收稿日期: 2025-06-26
  • 最后修改日期: 2025-08-25
  • 录用日期: 2025-08-23
  • 在线发布日期: 2025-08-24
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