CHINESE JOURNAL OF ENERGETIC MATERIALS
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HTPB/AOT/AP自熄火固体推进剂燃烧性能及增压熄火机理研究
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1.西北工业大学,固体推进全国重点实验室, 陕西 西安 710072;2.西安航天动力技术研究所, 陕西 西安 710025

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固体推进全国重点实验室开放项目资助


Research on Combustion Behavior and Pressurization-Induced Extinguished Mechanism of HTPB/AOT/AP Self-Extinguished Solid Propellant
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1.Northwestern Polytechnical University, National Key Laboratory of Solid Propulsion, Xi''an 710072, China;2.Xi’an Aerospace Solid Propulsion Technology Institute, Xi’an 710025, China

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    摘要:

    为研究自熄火固体推进剂燃烧性能并揭示增压熄火机理,使用丁二酸二辛酯磺酸钠(AOT)作为熄火控制剂制备了HTPB/AOT/AP自熄火固体推进剂,并对推进剂燃速、燃烧波结构、火焰形态和熄火燃面形貌等进行了实验表征。实验结果表明:AOT使推进剂在10 MPa以下的压强指数由0.37降低至-1.36,其中压强接近临界熄火压强时燃速由5.9 mm·s-1降低至2.9 mm·s-1,推进剂在压强增大至10 MPa时自熄火,压强更高时仍无法自持燃烧;压强接近临界熄火压强时,推进剂燃面上覆盖了厚度约230 μm的熔融层,降低了推进剂燃面温度和气相温度梯度,与2 MPa时相比,燃面温度由865 K降低至420 K,气相温度梯度由74.9 K·μm-1降低至0.19 K·μm-1;揭示了自熄火固体推进剂增压熄火机理,即AOT使推进剂表面覆盖较厚的熔融层,阻碍气相火焰对燃面的热反馈,降低燃面温度和凝聚相反应速率,最终导致推进剂无法自持燃烧而熄火。

    Abstract:

    In order to study the self-extinguished solid propellants combustion performance and the pressurization-induced extinguished mechanism, HTPB/AOT/AP self-extinguished solid propellants were prepared by using sodium dioctyl sulfosuccinate (AOT) as extinguishing agent. Experimental characterization of propellants burning rates, combustion wave structure, flame morphology and flame quenching burning surface topography was carried out. The experimental results show that AOT reduced the pressure exponent below 10 MPa from 0.37 to -1.36, with the burning rate decreasing from 5.9 mm·s-1 to 2.9 mm·s-1 as pressure approached the critical extinguished pressure; AOT caused the propellant to self-extinguished when the pressure increased to 10 MPa, with unsustainable combustion observed at higher pressures. As the pressure approached the critical extinction pressure, a molten layer approximately 230 μm thick to cover the propellant burning surface, reducing the burning surface temperature from 865 K to 420 K and the gaseous phase temperature gradient from 74.9 K·μm-1 to 0.19 K·μm-1 compared to when pressure at 2 MPa. The pressurization-induced extinguished mechanism of self-extinguished solid propellant has been revealed, where​ AOT causes a thicker molten layer to cover the propellant surface, obstructing heat feedback from the gaseous flame to the burning surface, reducing burning surface temperature and condensed phase reaction rate, and ultimately resulting in extinguishing due to failure to maintain self-sustained combustion.

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陈泽昕,刘林林,杨玉新,等. HTPB/AOT/AP自熄火固体推进剂燃烧性能及增压熄火机理研究[J]. 含能材料,DOI:10.11943/CJEM2025140.

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  • 收稿日期: 2025-06-26
  • 最后修改日期: 2025-08-19
  • 录用日期: 2025-08-23
  • 在线发布日期: 2025-08-23
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