CHINESE JOURNAL OF ENERGETIC MATERIALS
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聚叠氮缩水甘油醚合成及功能化研究进展
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中北大学环境与安全工程学院

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基金项目:

国家自然科学基金(22275170)


Progress in Synthesis and Functionalization of Glycidyl Azide Polymer
Author:
Affiliation:

School of Environmental and Safety Engineering, North University of China

Fund Project:

Grant support: National Natural Science Foundation of China (No. 22275170)

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    摘要:

    聚叠氮缩水甘油醚(GAP)作为一种含能聚合物,具有能量高和成膜性能好等特点,在推进剂、炸药等领域有广泛应用前景。综述了GAP合成工艺优化、GAP改性技术、GAP基含能热塑性弹性体(ETPE)及具有自修复功能的GAP基ETPE等方面的最新研究进展。分析了GAP两种合成方法,提出了发展安全、绿色、高效的GAP合成路线及现有优化工艺的完善与工程化应用是发展方向。针对GAP低温力学性能差、结构无规等问题,重点综述了共聚改性、互穿网络技术、微波辐射技术及氟化聚合物对GAP力学性能、热稳定性等方面的提升效果,提出了发展低成本改性工艺、深入研究GAP改性材料的长储性和环境适应性是推动改性GAP工程化发展的方向。综述了GAP基ETPE结构调控对力学性能、热稳定性和玻璃化转变温度的影响;特别是针对具有自修复功能的GAP基ETPE,国内外学者通过引入动态共价键和超分子作用机制,实现了对微缺陷的主动修复,显著提高了推进剂和炸药的力学性能与环境适应性。

    Abstract:

    As an energetic polymer, glycidyl azide polymer (GAP) has the characteristics of high energy and good film-forming performance, and has a wide application prospect in the fields of propellants, explosives and so on. The latest research progress in aspects such as the optimization of GAP synthesis process, GAP modification technology, GAP-based energetic thermoplastic elastomers (ETPE), and GAP-based ETPE with self-healing function were reviewed. Firstly, two synthetic methods of GAP were analyzed. It was proposed that the development directions were to develop a safe, green and efficient synthetic routes of GAP and the improvement and engineering application of the existing optimized processes. Secondly, in view of the poor low-temperature mechanical properties and irregular structure of GAP, the improvement effects of copolymerization modification, interpenetrating network technology, microwave radiation technology and fluoropolymers on the mechanical properties and thermal stability of GAP were mainly reviewed. It was proposed that developing low-cost modification processes and conducting in-depth research on the long-term storage and environmental adaptability of GAP-modified materials were the directions to promote the engineering development of modified GAP. Then, the influence of GAP-based ETPE structure regulation on mechanical properties, thermal stability and glass transition temperature was reviewed. Especially for GAP-based ETPE with self-healing function, scholars at home and abroad have achieved active repair of micro-defects by introducing dynamic covalent bonds and supramolecular interaction mechanism, significantly improving the mechanical properties and environmental adaptability of propellants and explosives.

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引用本文

邓文文,叶宝云,邱绵汲,等.聚叠氮缩水甘油醚合成及功能化研究进展[J].含能材料, 2025, 33(8):928-939. DOI:10.11943/CJEM2025085.
DENG Wen-wen, YE Bao-yun, QIU Mian-ji, et al. Progress in Synthesis and Functionalization of Glycidyl Azide Polymer[J]. Chinese Journal of Energetic Materials, 2025, 33(8):928-939. DOI:10.11943/CJEM2025085.

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  • 收稿日期: 2025-04-29
  • 最后修改日期: 2025-08-01
  • 录用日期: 2025-08-18
  • 在线发布日期: 2025-08-19
  • 出版日期: