CHINESE JOURNAL OF ENERGETIC MATERIALS
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端面电流密度对硝酸羟胺基电控固体推进剂燃烧性能的影响
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哈尔滨工业大学化工与化学学院空间电源国家重点实验室

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基金项目:

黑龙江省自然科学基金(YQ2024B004)


Effect of Surface Current Density on the Combustion Performance of HAN-ECSP
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State Key Laboratory of Space Power-Sources, School of Chemistry and Chemical Engineering, Harbin Institute of Technology

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Grant support: Natural Science Foundation of Heilongjiang Province of China(No. YQ2024B004)

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    摘要:

    为了探究端面电流密度对硝酸羟胺基电控固体推进剂(HAN-ECSP)燃烧性能的影响,通过改变HAN-ECSP与Cu电极的接触面积比调节推进剂一端的端面电流密度,对其分解产气性能、燃烧性能及燃烧启停性能进行研究。结果表明,当推进剂与电极阴极接触的端面电流密度较大时,推进剂的燃烧性能改善显著。然而,过小的有效接触面积会导致局部电流密度过高,可能引发电极损坏。因此,电极阳极和阴极与推进剂的最佳接触面积比为1∶0.4。相较于未更改电极与推进剂的接触面积时,推进剂与电极阴极接触的端面电流密度从301 A·m-2增至2466 A·m-2。通过产气和燃烧性能测试,端面电流密度增大了2165 A·m-2后,推进剂的产气总压强提高了4.8倍,产气速率提高了12倍,点火延迟时间从3.13 s降至0.76 s,质量燃烧速率从0.07 g·s-1增至0.22 g·s-1。并且在此端面电流密度下,推进剂依旧保持了出色的电控启停性能。

    Abstract:

    To investigate the effect of surface current density on the combustion performance of hydrazine nitrate-based electrically controlled solid propellant (HAN-ECSP), the contact area ratio between HAN-ECSP and Cu electrode was adjusted to regulate the surface current density of propellant. Decomposition, combustion and repeated on-off combustion performances were studied using gas collection and combustion test. The results indicate that the combustion performance of propellant is improved significantly as the increase of surface current density between the cathode and propellant. However, too small effective contact area could lead to excessive local current density, potentially causing the damage of electrode. Hence, the optimal contact area ratio between anode and cathode is 1∶0.4. Compared to unchanging the contact area between electrode and propellant, the surface current density rises from 301 to 2466 A·m-2. The results of gas decomposition pressure test and combustion indicate that the total gas pressure increases by 4.8 times, gas generation rate increases by 12 times, ignition delay time of propellant decreases from 3.13 to 0.76 s and mass combustion rate increases from 0.07 to 0.22 g·s-1, when the surface current density rises 2165 A·m-2. Moreover, the propellant still maintains excellent repeated on-off combustion performance at this surface current density.

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引用本文

刘富涵,鲁浩洋,夏德斌,等.端面电流密度对硝酸羟胺基电控固体推进剂燃烧性能的影响[J].含能材料, 2025, 33(8):892-897. DOI:10.11943/CJEM2025057.
LIU Fu-han, LU Hao-yang, XIA De-bin, et al. Effect of Surface Current Density on the Combustion Performance of HAN-ECSP[J]. Chinese Journal of Energetic Materials, 2025, 33(8):892-897. DOI:10.11943/CJEM2025057.

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  • 收稿日期: 2025-04-02
  • 最后修改日期: 2025-08-21
  • 录用日期: 2025-08-18
  • 在线发布日期: 2025-08-19
  • 出版日期: