CHINESE JOURNAL OF ENERGETIC MATERIALS
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不同温度和应力水平下HTPB复合固体推进剂的蠕变力学性能
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1.火箭军工程大学;2.内蒙动力机械研究所

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国家自然科学基金(22205259)


Creep Mechanical Properties of HTPB Composite Solid Propellant under Different Temperatures and Stress Levels
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1.Rocket Force University of Engineering, Xi'an , China;2.Inner Mongolia Power Machinery Institute

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    摘要:

    为研究三组元端羟基聚丁二烯(HTPB)复合固体推进剂在不同温度和应力水平下的蠕变力学性能,基于自研机械式蠕变性能测试装置、温湿度环境箱和高清相机等设备,开展了10 ℃、25 ℃、40 ℃和55 ℃ 4个环境温度下0.072~0.712 MPa应力水平范围内推进剂的蠕变力学响应测试,获得了应变-蠕变时间曲线及典型力学性能参数随试验环境温度和应力水平的变化规律,并建立了反映较宽加载条件下推进剂破坏性能的蠕变断裂时间主曲线。结果表明,随应力水平提高,推进剂的应变-蠕变时间曲线特性由3阶段转变为4阶段,而环境温度的升高可降低使曲线特性呈现4阶段的临界应力水平,且该应力水平满足指数型下降规律,其数值从10 ℃条件下的0.562 MPa降至55 ℃时的0.262 MPa,降低比值达53.38%;推进剂的初始蠕变柔量随环境温度升高而增大,但几乎不随应力水平升高而改变。当环境温度和应力水平均升高时,蠕变速率增大、蠕变断裂时间缩短、累积损伤程度增大、累积损伤速率加快,而断裂应变总体上仅对应力水平的改变比较敏感,且随应力水平提高而呈线性增加趋势。55 ℃、0.412 MPa作用下的蠕变速率约为10 ℃同等应力水平时的493倍,蠕变断裂时间约为25 ℃同等应力水平时的2.14%;基于不同环境温度下的蠕变断裂时间和应力水平的双对数试验数据,利用环境温度-应力水平等效关系,建立了推进剂的蠕变断裂时间主曲线,并获得了主曲线和温度移位因子的指数型数学表达式,采用该表达式经计算确保25 ℃条件下立式贮存的SRM药柱在15年内不发生蠕变断裂破坏的加载应力水平应低于0.2176 MPa。

    Abstract:

    To investigate the creep mechanical properties of tri-component hydroxyl-terminated polybutadiene (HTPB) composite solid propellant under different temperatures and stress levels, creep mechanical performance tests were conducted using a self-developed mechanical creep testing equipment, a temperature-humidity environmental chamber, and a high-definition camera. Tests were performed at environmental temperatures of 10 ℃, 25 ℃, 40 ℃ and 55 ℃, covering a stress range of 0.072 to 0.712 MPa . The strain-creep time curves were obtained, along with the variation patterns of typical mechanical property parameters with environmental temperature and stress level. A master curve for the creep rupture time, reflecting the propellant’s failure behavior under broad loading conditions, was established. The results indicate that, as the stress level increases, the characteristics of the propellant’s strain-creep time curve shift from three stages to four stages. Increasing environmental temperature reduces the critical stress level at which the four-stage curve characteristic exhibits, and this stress follows an exponential decay pattern, decreasing from 0.562 MPa at 10 ℃ to 0.262 MPa at 55 ℃ with a reduction ratio of 53.38%. The initial creep compliance increases with rising environmental temperature but remains almost unchanged with increasing stress level. When both environmental temperature and stress level increase, the creep rate increases, creep rupture time shortens, cumulative damage degree increases, and cumulative damage rate accelerates. In contrast, the fracture strain is primarily sensitive to changes in stress level and exhibits a linear increasing trend with increasing stress level. The creep rate under 55 ℃ and 0.412 MPa is approximately 493 times that under the same stress level at 10 ℃, and the creep rupture time is about 2.14% of that under the same stress level at 25 ℃. Finally, based on the double logarithmic test data of creep rupture time versus stress level under different environmental temperatures, and using the environmental temperature-stress level equivalence relationship, a master curve for propellant’s creep rupture time was established. At the same time, exponential mathematical expressions for this master curve and the temperature shift factor were obtained. Calculations using these expressions indicate that, to ensure a vertically stored SRM grain does not experience creep rupture failure within 15 years at 25 ℃, the loading stress level should be lower than 0.2176 MPa.

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王哲君,张砚珅,强洪夫,等. 不同温度和应力水平下HTPB复合固体推进剂的蠕变力学性能[J]. 含能材料,DOI:10.11943/CJEM2025049.

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  • 收稿日期: 2025-03-28
  • 最后修改日期: 2025-06-16
  • 录用日期: 2025-06-09
  • 在线发布日期: 2025-06-11
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