To improve the safety of the charging process of molecular perovskite energetic material （DAP-4）， spherical granulation of DAP-4-based energetic composite microspheres was realized by altering the composite ratio of the bonding agents， Glycidyl Azide Polymer （GAP） and nitrocellulose （NC） （constituting 2% of the mass of DAP-4） using the coaxial droplet microfluidic technology. The macro and micro morphology， crystal structure， thermal properties， combustion properties， and mechanical sensitivity of the samples were tested and analyzed by scanning electron microscope， X-ray diffractometer， differential thermal scanning calorimeter， thermogravimetric analyzer， high-speed photography， impact sensitivity tester and friction sensitivity tester. The results indicate that DAP-4 has the best sphericity when the ratio of GAP to NC is 4∶1. The crystal structure of DAP-4 is not changed after spheroidizing granulation， and the peak temperature of thermal decomposition is slightly advanced. The combustion time of DAP-4 microspheres is slightly longer than that of raw materials， overall with a very stable continuous combustion， retaining its excellent combustion performance. The GN41 microspheres can significantly improve fluidity while reducing mechanical sensitivity and improving the safety of the charging process.