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高低温循环保存下片状变燃速发射药的燃烧稳定性
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1.南京理工大学化学与化工学院,江苏 南京 210094;2.南京理工大学 特种能源材料教育部重点实验室,江苏 南京 210094;3.泸州北方化学工业有限公司,四川 泸州 646003

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Combustion Stability of Flake Variable Burning Rate Propellant after High and Low Temperature Cycling
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1.School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China;2.Key Laboratory of Special Energy Materials, Ministry of Education, Nanjing University of Science and Technology, Nanjing 210094, China;3.Luzhou North Chemical Industry Co., Ltd, Luzhou 646605, China

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    摘要:

    为了研究片状变燃速发射药在高低温循环保存下的燃烧稳定性,将样品形貌及燃烧性能变化作为考察依据,以70 ℃高温10 h,-50 ℃低温10 h为一个循环周期,对片状变燃速发射药样品进行了20次高低温循环保存。通过光学显微镜观察了高低温循环前后片状变燃速发射药的表面形貌,利用密闭爆发器测试了高温50 ℃、常温20 ℃、低温-40 ℃下高低温循环前后片状变燃速发射药的燃烧性能。显微观测发现经高低温循环后,片状变燃速发射药表层气泡扩大增多,发射药断面出现塑性形变现象,内外层界面结合保持紧密,没有开裂与脱黏。密闭爆发器试验反映了该类型发射药经过高低温循环后,高温、常温、低温下动态活度曲线与高低温循环前都基本重合,动态活度变化值ΔL最大值出现在低温条件下,为2.57%,能量渐增性释放规律基本不变。高低温循环下,片状变燃速发射药在高压常温-低温阶段的燃速温度系数对比原样在相同条件下显著降低,高温与低温下片状变燃速发射药的压力指数差距对比原样在相同条件下减小。结果表明,片状变燃速发射药在高低温循环条件下界面和燃烧性能稳定,具有较好的变温贮存稳定性。

    Abstract:

    In order to investigate the combustion stability of flake variable burning rate propellant under high and low temperature cycle preservation, based on the morphology of samples and the change of combustion performance, a 20 time thermal cycling treatment was carried out, in which samples were separately stored at 70 ℃ and -50 ℃ for 10 h as one cycle. The surface and section morphology of propellant was observed via optical microscope, and the combustion performance at 50 ℃, 20 ℃, -40 ℃ was tested by closed bomb. Microscopic observation shows that after thermal cycling treatment, the bubbles on the surface increase and the section of propellant becomes lumpy and uneven due to plastic deformation, while the interface between the inner and outer layers remains tight without visible cracks. The combustion performance basically unchanged after thermal cycling treatment, and the dynamic activity curves nearly overlap, for which the maximum ΔLa is 2.57% at low temperature. After thermal cycling treatment, the temperature coefficient under high-pressure from normal to low temperature is significantly lower than that of the original under the same conditions, and the difference in pressure index of the flake variable burning rate propellant at high temperature and low temperature is smaller than that of the original under the same conditions. Attributed to bound interface and combustion consistency, flake variable burning rate propellant has good storage stability under different temperatures.

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引用本文

赵先正,刘详,丁亚军,等.高低温循环保存下片状变燃速发射药的燃烧稳定性[J].含能材料, 2023, 31(9):903-909. DOI:10.11943/CJEM2022209.
ZHAO Xian-zheng, LIU Xiang, DING Ya-jun, et al. Combustion Stability of Flake Variable Burning Rate Propellant after High and Low Temperature Cycling[J]. Chinese Journal of Energetic Materials, 2023, 31(9):903-909. DOI:10.11943/CJEM2022209.

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  • 收稿日期: 2022-08-15
  • 最后修改日期: 2023-07-13
  • 录用日期: 2023-07-05
  • 在线发布日期: 2023-07-12
  • 出版日期: 2023-09-25