CHINESE JOURNAL OF ENERGETIC MATERIALS
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三唑类含能化合物研究进展
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中北大学环境与安全工程学院, 山西 太原 030051

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Review on Energetic Compounds Based on Triazoles
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School of Environment and Safety Engineering,North University of China, Taiyuan 030051, China

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    摘要:

    三唑类含能化合物是近些年发展的一类新型含能化合物,具有高生成焓、高氮含量和高热稳定性的特点。本文从分子结构出发,综述了单三唑类、双三唑类、吡唑基三唑类、噁二唑基三唑类和四唑基三唑类等40余系列含能化合物的最新合成研究成果,对部分化合物性能进行了阐述。并结合三唑类含能化合物的性能特点,指出基于构效关系设计新型三唑化合物,平衡能量-安全间的矛盾关系,是发展高能钝感三唑含能化合物的有效策略;在此基础上,设计合成笼状三唑含能化合物是较具潜力的发展方向,并提出筛选综合性能优异的三唑化合物开展应用研究。

    Abstract:

    Triazole-based energetic compound is a new class of energetic materials with the features of high heat of formation, high nitrogen content and good thermal stability. In this paper, the latest research achievements on synthesis of more than 40 series of energetic compounds based on mono-triazole, bis-triazole, pyrazole-triazole, oxadiazole-triazole and tetrazole-triazole were reviewed, and the performances of some compounds were introduced in detail. It is showed that designing new triazole-based energetic compounds based on structure-performance relationship and balancing energy and safety are the effective strategy to develop high energy and insensitive energetic compounds. On this basis, design and synthesis of cage triazole-based energetic compounds are the promising developing direction. The application study of existing triazole-based energetic compounds with outstanding overall performance is proposed.

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引用本文

刘洋,陈亚红,苟瑞君,等.三唑类含能化合物研究进展[J].含能材料, 2023, 31(5):485-507. DOI:10.11943/CJEM2022131.
LIU Yang, CHEN Ya-hong, GOU Rui-jun, et al. Review on Energetic Compounds Based on Triazoles[J]. Chinese Journal of Energetic Materials, 2023, 31(5):485-507. DOI:10.11943/CJEM2022131.

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历史
  • 收稿日期: 2022-05-13
  • 最后修改日期: 2022-08-30
  • 录用日期: 2022-08-23
  • 在线发布日期: 2022-08-26
  • 出版日期: 2023-05-25