CHINESE JOURNAL OF ENERGETIC MATERIALS
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B-GAP基推进剂药浆流变特性和固化动力学研究
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1.中北大学环境与安全工程学院, 山西 太原 030051;2.山西省超细粉体工程技术研究中心, 山西 太原 030051;3.西安近代化学研究所, 陕西 西安 710065

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国防基础性军工科研院所稳定支持专项(SYJJ44)


Research on Rheological Properties and Curing Kinetics of B-GAP-based Propellant Slurry
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Affiliation:

1.School of Environment and Safety Engineering, North University of China, Taiyuan 030051, China;2.Shanxi Engineering Technology Research Center for Ultrafine Powder, Taiyuan 030051, China;3.Xi′an Modern Chemistry Research Institute, Xi′an 710065, China

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    摘要:

    为了研究支化聚叠氮缩水甘油醚(B-GAP)基推进剂的流变特性和固化反应过程,采用流变学研究方法对药浆进行了测试,研究了在50,55,60 ℃和65 ℃下药浆粘度随剪切速率及其模量随时间的变化规律。研究结果表明:B-GAP基推进剂药浆具有剪切变稀特性,属于假塑性非牛顿流体;推进剂药浆固化反应速率随着固化反应的进行而增加,在固化度为0.3时达到最大值,之后反应速率开始减小直至为零;温度对于推进剂固化反应动力学有较大影响,在一定温度范围内,固化反应速率峰值随着温度的升高而增加,储能模量最大值随着温度的升高而减小;基于幂律方程和Arrhenius方程计算得到了B-GAP药浆的本构方程和固化反应动力学方程。

    Abstract:

    To study the rheological properties and to cure the reaction process of branched polyglycidyl azide (B-GAP)-based propellent, the slurries were tested by rheological research methods, and the changes of viscosity with shear rate and modulus with time at 50, 55, 60 ℃ and 65 ℃ were studied. The results indicate: B-GAP propellant slurry has a shear thinning properties and belongs to pseudoplastic non-Newtonian fluid; The curing reaction rate of the propellant slurry increases as the curing reaction progresses, reaching a maximum value when the curing degree is 0.3, and then the reaction rate begins to decrease until zero; Temperature has a great influence on the kinetics of propellant curing reaction. Within a certain temperature range, the peak value of the curing reaction rate increases with the increase of temperature, and the maximum value of storage modulus decreases with the increase of temperature; Based on the power law equation and Arrhenius equation, the constitutive equation and curing kinetic reaction equation of B-GAP slurry was obtained.

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卢鑫浩,叶宝云,程王健,等. B-GAP基推进剂药浆流变特性和固化动力学研究[J].含能材料, 2022, 30(11):1083-1089. DOI:10.11943/CJEM2021324.
LU Xin-hao, YE Bao-yun, CHENG Wang-jian, et al. Research on Rheological Properties and Curing Kinetics of B-GAP-based Propellant Slurry[J]. Chinese Journal of Energetic Materials, 2022, 30(11):1083-1089. DOI:10.11943/CJEM2021324.

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  • 收稿日期: 2021-12-06
  • 最后修改日期: 2022-09-29
  • 录用日期: 2022-05-23
  • 在线发布日期: 2022-09-29
  • 出版日期: 2022-11-25