1²，1⁴，1⁶，3⁴，3⁶，5²，5⁴，5⁶，7⁴，7⁶-decanitro-2，4，6，8-tetraoxa-1，3，5，7（1，3）-tetrabenzenacyclooctaphane-1⁵，5⁵-diol （ZXC-51） was obtained from phloroglucinol and 1，3-difluorobenzene through nitration and cyclization. A series of calixarene energetic salts were received by the reaction between ZXC-51 and different organic base. The single crystal structures of compound ZXC-51 and its four salts were proved by X-ray single crystal diffraction analysis. And the structures of these compounds were also characterized by NMR and elemental analysis. Meanwhile their thermal properties were also analyzed by differential scanning calorimetry. The detonation and safety performance of ZXC-51 were studied. The results show that its theoretical detonation velocity and detonation pressure are 8193 m·s^-1 and 31.18 GPa respectively. And its impact sensitivity is 36 J and the friction sensitivity is more than 360 N.