CHINESE JOURNAL OF ENERGETIC MATERIALS
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NEPE推进剂无损型贮存寿命预估
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作者单位:

1.海军航空大学 岸防兵学院, 山东 烟台 264001;2.海军航空大学 航空基础学院, 山东 烟台 264001

作者简介:

孔令泽(1995-),男,汉族,博士研究生,主要从事固体火箭发动机使用工程的研究。e-mail:konglingze42@163.com

通讯作者:

董可海(1973-),男,汉族,副教授,主要从事固体火箭发动机使用工程的研究。e-mail:dongkehai1973@sina.com

基金项目:

武器装备预先研究项目基金(No.51328050101)


Non-destructive Storage Life Prediction of NEPE Propellant
Author:
Affiliation:

1.College of coast defense arm, Naval Aeronautical University, Yantai 264001, China;2.College of aviation fundamentals, Naval Aeronautical University,Yantai 264001, China

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    摘要:

    为了实现对硝酸酯增塑聚醚(NEPE)推进剂药柱贮存寿命进行预估时的测量无损性,通过对施加10%定压缩应变的NEPE推进剂进行高温热加速老化实验、气体含量监测实验、单向拉伸力学性能实验,基于相关性分析和寿命预估模型,提出了一种以特征气体含量变化为基础数据的无损型寿命预估模型。结果表明,NEPE推进剂贮存老化过程中,CO气体释放量最大,不同温度条件下的释放量均达到1300 mg以上,且其和NO气体均呈现老化初期释放量增长缓慢,后期迅速增加的规律,HCl气体释放量在老化初期和后期增长较快,老化中期增长较慢;老化初期最大抗拉强度σm和最大延伸率εm小幅增大,老化中期前者小幅震荡,后者逐渐增大,老化后期两者均急剧减小;不同温度条件下CO气体释放量与最大抗拉强度关联度值最大,为0.93~0.95,且两者存在单一相关性;基于传统老化寿命预估模型和改进的老化寿命预估模型,建立了四种NEPE推进剂寿命预估方法,通过相关性系数比较和预估结果分析,得出以CO气体释放量作为预估参数的改进型寿命预估模型的相关性系数最大,寿命预估结果最为有效。

    Abstract:

    In order to realize the non-destructive measurement when predicting the storage life of nitrate ester plasticized polyether (NEPE) propellant, the high temperature accelerated aging, gas content monitoring and uniaxial tensile mechanical property experiment were carried out on NEPE propellant with 10% constant compression strain . The non-destructive storage life prediction model based on characteristic gas contents was proposed through correlation analysis and remaining life prediction model. The results show that during the storage and aging processes, the total amount of CO gas is the largest, reaching more than 1300 mg at different temperatures. The generating rates of NO and CO are growing slowly in the early aging period, and growing faster in the late period. The generating rate of HCl increases rapidly during the eraly and late aging period and slowly in the middle. Maximum tensile strength σm and maximum elongation εm increase slightly in the early aging period, the former oscillates slightly and the latter gradually increases in the middle period, and both of them decrease sharply in the late period. The correlation between the contents of CO and the maximum tensile strength is largest and there is a single correlation between them at different temperatures. The maximum correlation value reaches about 0.93-0.95. Four life prediction methods of NEPE propellant are established based on traditional and improved aging life prediction model, tensile strength and CO content. The maximum correlation coefficient and estimation results show that the improved prediction model based on the content of CO gas release is most effective.

    表 4 系数a、b的单因素方差分析结果Table 4 Analysis of variance (ANOVA) results of a and b
    表 2 长周期不同温度下三种特征气体含量最大值Table 2 Maximum contents of three kinds of characteristic gases in long period at different temperatures
    表 3 特征气体含量与最大抗拉强度关联度Table 3 Correlation between characteristic gas content and maxium tensile strength
    图5 灰色关联分析法计算流程Fig.5 Calculation process of grey relational analysis
    表 6 NEPE推进剂贮存寿命预估结果Table 6 Estimated results of NEPE propellant storage life a
    表 1 四种老化温度性能采样点Table 1 Performance sampling time point at four temperatures
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引用本文

孔令泽,董可海,唐岩辉,等. NEPE推进剂无损型贮存寿命预估[J].含能材料, 2022, 30(2):163-170. DOI:10.11943/CJEM2021056.
KONG Ling-ze, DONG Ke-hai, TANG Yan-hui, et al. Non-destructive Storage Life Prediction of NEPE Propellant[J]. Chinese Journal of Energetic Materials, 2022, 30(2):163-170. DOI:10.11943/CJEM2021056.

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  • 收稿日期: 2021-03-19
  • 最后修改日期: 2021-04-14
  • 录用日期: 2021-05-27
  • 在线发布日期: 2022-03-17
  • 出版日期: 2022-02-25