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裂解态正癸烷点火延迟时间的理论研究(英)
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天津大学化学工学院,教育部绿色化学技术重点实验室, 化学科学与工程协同创新中心(天津), 天津 300072

作者简介:

LIU Guo-zhu (1979-), Male, Professor, engaged in hydrocarbon fuel pyrolysis. e-mail: gliu@tju.edu.cn

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Theoretical Study on Ignition Delay Time of Thermally Cracked n-Decane
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School of Chemical Engineering and Technology, Key Laboratory for Green Chemical Technology of Ministry of Education, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300072, China

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    摘要:

    在先进飞行器发动机中,吸热碳氢燃料在进入燃烧室之前会发生热裂解反应,生成未反应燃料和小分子裂解产物的混合物(称为裂解态燃料)。本工作研究了在1300~1800 K、0.1~3.0 MPa和当量比为1.0的条件下,不同的裂解转化率、裂解压力、点火压力和自由基对正癸烷裂解着火特性的影响。通过采用一种精确的组合机理,从理论上计算了流动反应器中3.0和5.0 MPa下正癸烷裂解组分,与文献中的实验结果吻合较好。结果表明,正癸烷在 3 MPa和5 MPa下裂解的出口转化率分别为46.2%和 58.8%,裂解产物分布一致,但乙烯的含量随着压力的升高明显的降低,而烷烃含量随着压力的增大而增加。尽管自由基总体含量很低,但在3 MPa条件下裂解产物中的自由基浓度依然高于5 MPa条件下。对于点火延迟时间的计算结果则表明,裂解态正癸烷的点火延迟时间随着转化率的增大而延长,且在5 MPa下随着转化率的变化更明显。相同转化率下,5 MPa下的裂解态正癸烷的点火延迟时间比3 MPa下更短。此外,与无自由基的裂解正癸烷相比,裂解正癸烷中自由基的存在可以加速着火过程,转化率小于40%时,着火延迟时间缩短15%以上。

    Abstract:

    Endothermic hydrocarbon fuels undergo thermal cracking before entering the combustion chamber and can produce a mixture of unreacted fuels and pyrolysis products (i.e. cracked fuels). The objective of this work is to investigate the effects of pyrolysis conversions, pyrolysis pressures, ignition pressures and free radicals on ignition characteristics of cracked n-decane over temperature of 1300-1800 K, pressure of 0.1-3.0 MPa and equivalence ratio of 1.0. Components of the thermally cracked n-decane at 3.0 and 5.0 MPa in a flow reactor were calculated theoretically using an accurately combined mechanism, which are in good agreement with the experimental results in literature. The results showed the conversion rates of n-decane cracking at 3 and 5 MPa are 46.2% and 58.8%, respectively. The distribution of cracking products is consistent, but the ethylene content decreases with the increase of pressure, while the alkane content increases with the increase of pressure. Meanwhile, the content of free radicals at 3 MPa is slightly higher than that at 5 MPa, but the content of free radicals is very low. Ignition delay time increases with the decreasing of n-decane conversion and pyrolysis pressure, while higher ignition pressure can shorten it significantly. Furthermore, the presence of free radicals in cracked n-decane could accelerate the ignition process with ignition delay time shortening more than 15% when the conversion was less than 40%, compared with that of cracked n-decane without radicals.

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引用本文

王鸿燕,裴闪闪,王莅,等.裂解态正癸烷点火延迟时间的理论研究(英)[J].含能材料, 2020, 28(5):398-406. DOI:10.11943/CJEM2020012.
WANG Hong-yan, PEI Shan-shan, WANG Li, et al. Theoretical Study on Ignition Delay Time of Thermally Cracked n-Decane[J]. Chinese Journal of Energetic Materials, 2020, 28(5):398-406. DOI:10.11943/CJEM2020012.

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历史
  • 收稿日期: 2020-01-14
  • 最后修改日期: 2020-03-28
  • 录用日期: 2020-03-19
  • 在线发布日期: 2020-03-26
  • 出版日期: 2020-05-25